{"title":"某些膦叔和砷叔铱(III)配合物的光化学异构化及相关反应","authors":"P. Brookes, C. Masters, B. Shaw","doi":"10.1039/J19710003756","DOIUrl":null,"url":null,"abstract":"The photochemical isomerization of complexes of the types mer-[IrX3L3], [IrHX2L3], and [IrX3(CO)L2](X = Cl, Br, or I; L = tertiary phosphine) are reported. Complexes of the type fac-[IrX3(PEt3)3](X = CNO, SCN, or N3) have been made from mer-[IrCl3(PEt3)3] by a light-induced reaction. The complexes mer-[IrCl3L3](L = PEt3, PBun3, or AsMe2Ph) react with PMe2Ph in light to give [IrCl3L2(PMe2Ph)]. Some reactions of complexes of the type fac-[IrX3L3] are described.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"124 1","pages":"3756-3760"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"14","resultStr":"{\"title\":\"Photochemical isomerizations and related reactions of some tertiary phosphine- and tertiary arsine-iridium(III) complexes\",\"authors\":\"P. Brookes, C. Masters, B. Shaw\",\"doi\":\"10.1039/J19710003756\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The photochemical isomerization of complexes of the types mer-[IrX3L3], [IrHX2L3], and [IrX3(CO)L2](X = Cl, Br, or I; L = tertiary phosphine) are reported. Complexes of the type fac-[IrX3(PEt3)3](X = CNO, SCN, or N3) have been made from mer-[IrCl3(PEt3)3] by a light-induced reaction. The complexes mer-[IrCl3L3](L = PEt3, PBun3, or AsMe2Ph) react with PMe2Ph in light to give [IrCl3L2(PMe2Ph)]. Some reactions of complexes of the type fac-[IrX3L3] are described.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":\"124 1\",\"pages\":\"3756-3760\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"14\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710003756\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710003756","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Photochemical isomerizations and related reactions of some tertiary phosphine- and tertiary arsine-iridium(III) complexes
The photochemical isomerization of complexes of the types mer-[IrX3L3], [IrHX2L3], and [IrX3(CO)L2](X = Cl, Br, or I; L = tertiary phosphine) are reported. Complexes of the type fac-[IrX3(PEt3)3](X = CNO, SCN, or N3) have been made from mer-[IrCl3(PEt3)3] by a light-induced reaction. The complexes mer-[IrCl3L3](L = PEt3, PBun3, or AsMe2Ph) react with PMe2Ph in light to give [IrCl3L2(PMe2Ph)]. Some reactions of complexes of the type fac-[IrX3L3] are described.
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