某些膦叔和砷叔铱(III)配合物的光化学异构化及相关反应

P. Brookes, C. Masters, B. Shaw
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引用次数: 14

摘要

mer-[IrX3L3]、[IrHX2L3]和[IrX3(CO)L2]类型配合物的光化学异构化(X = Cl、Br或I);L =叔膦)。以mer-[IrCl3(PEt3)3]为原料,通过光诱导反应制备了fac-[IrX3(PEt3)3](X = CNO, SCN或N3)型配合物。配合物mer-[IrCl3L3](L = PEt3, PBun3,或AsMe2Ph)在光照下与PMe2Ph反应生成[IrCl3L2(PMe2Ph)]。描述了fac-[IrX3L3]型配合物的一些反应。
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Photochemical isomerizations and related reactions of some tertiary phosphine- and tertiary arsine-iridium(III) complexes
The photochemical isomerization of complexes of the types mer-[IrX3L3], [IrHX2L3], and [IrX3(CO)L2](X = Cl, Br, or I; L = tertiary phosphine) are reported. Complexes of the type fac-[IrX3(PEt3)3](X = CNO, SCN, or N3) have been made from mer-[IrCl3(PEt3)3] by a light-induced reaction. The complexes mer-[IrCl3L3](L = PEt3, PBun3, or AsMe2Ph) react with PMe2Ph in light to give [IrCl3L2(PMe2Ph)]. Some reactions of complexes of the type fac-[IrX3L3] are described.
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