耐久的自清洁纳米二氧化钛超亲水涂层,具有防雾性能

A.M. Syafiq, Vengadaesvaran Balakrishnan, Nasrudin Abd. Rahim
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引用次数: 1

摘要

目的设计具有超亲水性、自洁性和防雾性的纳米二氧化钛(TiO2)涂层体系,并在玻璃基板上具有较强的附着力。设计/方法/方法采用简单的溶胶-凝胶法,采用两种亲水性材料,如TiO2纳米颗粒作为填料和亲水性共聚物Pluronic F-127。将制备好的溶液通过浸渍和喷涂技术涂在玻璃上,然后在室温下干燥。结果纳米tio2超亲水涂层的水接触角达到4.9°±0.5°。超亲水涂层对浓糖浆和亚甲基蓝具有良好的自清洁效果,其中薄层水将污垢污染物冲走。纳米二氧化钛涂层具有良好的防雾性能,当涂层玻璃置于热雾蒸汽上10分钟时,其透明度保持在89%左右。雾滴凝结成水膜,使光能透过玻璃。在500、800和1200 mN的划痕载荷作用下,涂层玻璃的强附着力在划痕处没有完全失效。研究的局限性和意义研究结果将有助于开发适用于建筑玻璃和光伏板的自清洁超亲水性涂层。实际意义本发明的纳米TiO2涂层是由亲水性有机共聚物-无机TiO2网络相结合而成,具有优异的超亲水性、最佳的自清洁能力和优异的防雾性能。社会意义该研究结果将对建筑玻璃窗的居民有用,该应用将减少灰尘积聚,并使玻璃长时间保持清洁。纳米tio2超亲水涂层的合成,可喷涂在大型玻璃板上,室温固化。
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Durable self-cleaning nano-titanium dioxide superhydrophilic coating with anti-fog property
Purpose This paper aims to design the nano-titanium dioxide (TiO2) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong adhesion on glass substrate. Design/methodology/approach Two hydrophilic materials have been used such as TiO2 nanoparticles as fillers and hydrophilic copolymer, Pluronic F-127 by using simple sol–gel approach. The prepared solution was applied onto glass through dip- and spray-coating techniques and then left for drying at ambient temperature. Findings The nano-TiO2 superhydrophilic coating has achieved the water contact angle of 4.9° ± 0.5°. The superhydrophilic coating showed great self-cleaning effect against concentrated syrup and methylene blue where thin layer of water washes the dirt contaminants away. The nano-TiO2 coating exhibits great antifog performance that maintains high transparency of around 89% when the coated glass is placed above hot-fog vapor for 10 min. The fog droplets were condensed into water film which allowed the transmission of light through the glass. The strong adhesion of coated glass shows no total failure at scratch profile when impacted with scratch load of 500, 800 and 1,200 mN. Research limitations/implications Findings will be useful in the development of self-cleaning superhydrophilic coating that is applicable on building glass and photovoltaic panel. Practical implications The developed nano-TiO2 coating is developed by the combination of hydrophilic organic copolymer–inorganic TiO2 network to achieve great superhydrophilic property, optimum self-cleaning ability and supreme antifog performance. Social implications The findings will be useful for residents in building glass window where the application will reduce dust accumulation and keep the glass clean for longer period. Originality/value The synthesis of nano-TiO2 superhydrophilic coating which can be sprayed on large glass panel and cured at ambient temperature.
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