添加剂细水雾对磷酸铁锂电池火灾的灭火实验研究

Xun Li, Shun-bing Zhu, Weiqian Zhuang, Xuetong Hao
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引用次数: 1

摘要

为了减少动力锂离子电池热失控造成的危害,利用自建的锂电池燃烧试验平台进行了灭火实验。通过测试表面活性剂十二烷基硫酸钠(SDS)和聚氧乙烯蓖麻油酸酯(EL-20)水雾的最佳灭火浓度、灭火时间和吸烟能力,将两种细水雾添加剂按1:1复配,形成的二元化合物再次作为水雾添加剂进行实验研究。结果表明,所选细水雾添加剂对动力锂离子电池的火灾均有不同程度的抑制作用,但灭火性能不同。一般情况下,当添加剂浓度为3%时,含添加剂的水雾灭火时间最短;含有SDS+EL-20复合添加剂的水雾灭火效果优于含有SDS和EL-20单一添加剂的水雾灭火效果。与纯水雾相比,含有SDS和EL-20的水雾对火灾烟气中CH4等有害气体有明显的增溶和吸收作用。
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Experimental study on the suppression of fire in lithium iron phosphate battery with additive water mist
In order to reduce the harm caused by the thermal runaway of the power lithium-ion battery, the fire-extinguishing experiment was carried out using the self-built lithium battery combustion test platform. By testing the optimum fire extinguishing concentration, fire extinguishing time and smoke absorption capacity of the surfactant water mist containing sodium dodecyl sulfate (SDS) and polyoxyethylene ricinoleate (EL-20), then two kinds of fine water mist additives the 1:1 compounding was carried out, and the formed binary compound was again subjected to experimental research as a water mist additive. The results show that the selected water mist additives can inhibit the power lithium-ion battery fire to varying degrees, but the fire-extinguishing performance is different. In general, the water mist containing the additive has the shortest fire extinguishing time when the additive concentration is 3%; the fire extinguishing effect of the water mist containing the SDS+EL-20 composite additive is better than that of the single additive containing SDS and EL-20. Compared with pure water mist, the water mist containing SDS and EL-20 has obvious solubilization and absorption effect on harmful gases such as CH4, in fire smoke.
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