{"title":"光活性茶树内酯A和茶树碱的全合成","authors":"N. Kato, Hideyuki Nishikawa, H. Takeshita","doi":"10.15017/6622","DOIUrl":null,"url":null,"abstract":"Optically-active diplophyllolide A and diplophyllin, mould metabo lites having the opposite absolute configuration to the metabolites of higher plants, were synthesized. Diplophyllolide A and diplophyllin (la and Ib)2) are components of plagiospirolides A and B (2a and 2b), isolated from Plagiochila moritziana. 3) The planar structures of la and Ib are equivalent to the 2-deoxo derivative of pinnatifidin, isolated from Helenium pinnatijidum, 4) and 1-deoxy derivative of ivangustin, isolated from Iva angustijolia, 5) and both have partially been synthesized from artemisin. 6 )","PeriodicalId":22886,"journal":{"name":"The reports of Institute of Advanced Material Study Kyushu University","volume":"37 1","pages":"29-38"},"PeriodicalIF":0.0000,"publicationDate":"1993-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"The Total Synthesis of Optically-Active Diplophyllolide A and Diplophyllin\",\"authors\":\"N. Kato, Hideyuki Nishikawa, H. Takeshita\",\"doi\":\"10.15017/6622\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Optically-active diplophyllolide A and diplophyllin, mould metabo lites having the opposite absolute configuration to the metabolites of higher plants, were synthesized. Diplophyllolide A and diplophyllin (la and Ib)2) are components of plagiospirolides A and B (2a and 2b), isolated from Plagiochila moritziana. 3) The planar structures of la and Ib are equivalent to the 2-deoxo derivative of pinnatifidin, isolated from Helenium pinnatijidum, 4) and 1-deoxy derivative of ivangustin, isolated from Iva angustijolia, 5) and both have partially been synthesized from artemisin. 6 )\",\"PeriodicalId\":22886,\"journal\":{\"name\":\"The reports of Institute of Advanced Material Study Kyushu University\",\"volume\":\"37 1\",\"pages\":\"29-38\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1993-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The reports of Institute of Advanced Material Study Kyushu University\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15017/6622\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The reports of Institute of Advanced Material Study Kyushu University","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15017/6622","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The Total Synthesis of Optically-Active Diplophyllolide A and Diplophyllin
Optically-active diplophyllolide A and diplophyllin, mould metabo lites having the opposite absolute configuration to the metabolites of higher plants, were synthesized. Diplophyllolide A and diplophyllin (la and Ib)2) are components of plagiospirolides A and B (2a and 2b), isolated from Plagiochila moritziana. 3) The planar structures of la and Ib are equivalent to the 2-deoxo derivative of pinnatifidin, isolated from Helenium pinnatijidum, 4) and 1-deoxy derivative of ivangustin, isolated from Iva angustijolia, 5) and both have partially been synthesized from artemisin. 6 )
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
