建筑玻璃耐雾自洁聚二甲基硅氧烷/纳米碳酸钙-二氧化钛涂层的研制

A.M. Syafiq, Nasrudin Abd. Rahim, Vengadaesvaran Balakrishnan, A. K. Pandey
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摘要

目的介绍了以疏水聚二甲基硅氧烷(PDMS)聚合物和纳米碳酸钙(nano-CaCO3)、二氧化钛(TiO2)为原料,合成具有防雾性能的自清洁涂层的简单工艺。PDMS/纳米caco3 - tio2的合成方法是基于溶胶-凝胶法。在50℃的温度下,PDMS与纳米颗粒之间的交联是由共价键驱动的。以3-氨基丙基三乙氧基硅烷为粘结剂,使纳米颗粒附着在聚合物基体上。采用浸渍法和喷涂法两种制备方法。结果制备的镀膜玻璃满足标准的自洁性和耐雾性要求。自清洁测试BS EN 1096-5:2016,涂层玻璃在倾斜角度为10°时显示粉尘雾霾值在20%-25%左右。在防雾测试中,镀膜玻璃的雾霾值在2%以下,光泽度在85%以上。所得结果完全达到ASTM F659-06协议的标准防雾值。研究的局限性/意义研究结果将为建筑玻璃提高建筑的能源效率、清洁性能和环境友好性提供基础设施支持。实际意义本研究提出了采用疏水聚合物和纳米caco3、纳米tio2的简单合成方法,可使建筑玻璃获得最佳的低倾角自清洁性能和抗雾性能。社会意义研究结果对建筑公司、清洁建筑公司和政府部门具有很大的应用潜力。由于人工成本、时间和人工清洁过程的安全性,该项目每年可减少约20%的能源消耗。采用简单的合成工艺和制造方法,研制出用于建筑玻璃的耐雾自洁涂层。
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Development of self-cleaning polydimethylsiloxane/nano-calcium carbonate-titanium dioxide coating with fog-resistance response for building glass
Purpose This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium carbonate (nano-CaCO3) and titanium dioxide (TiO2). Design/methodology/approach The synthesis method of PDMS/nano-CaCO3-TiO2 is based on sol-gel process. The crosslinking between PDMS and nanoparticles is driven by the covalent bond at temperature of 50°C. The 3-Aminopropyltriethoxysilane is used as binder for nanoparticles attachment in polymer matrix. Two fabrication methods are used, which are dip- and spray-coating methods. Findings The prepared coated glass fulfilled the requirement of standard self-cleaning and fog-resistance performance. For the self-cleaning test BS EN 1096-5:2016, the coated glasses exhibited the dust haze value around 20%–25% at tilt angle of 10°. For the antifog test, the coated glasses showed the fog haze value were below 2% and the gloss value were above 85%. The obtained results completely achieved the standard antifog value ASTM F659-06 protocol. Research limitations/implications Findings will provide an infrastructure support for the building glass to enhance building’s energy efficiency, cleaning performance and friendly environment. Practical implications This study proposed the simple synthesis method using hydrophobic polymer and nano-CaCO3 and nano-TiO2, which can achieve optimum self-cleaning property at low tilt angle and fog-resistance performance for building glass. Social implications The research findings have high potential for building company, cleaning building company and government sector. The proposed project capable to reduces the energy consumption about 20% per annum due to labor cost, time-consuming and safety during manual cleaning. Originality/value The novel method to develop self-cleaning coating with fog-resistance using simple synthesis process and fabrication method for building glass application.
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