共晶Sn9Zn焊料与镀镍界面相互作用动力学

Yao-Ling Kuo, Kwang-Lung Lin
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引用次数: 1

摘要

在230 ~ 290℃的温度范围内,研究了液态共晶Sn9Zn焊料与电镀Ni层之间的界面相互作用。相互作用生成了多种Ni-Zn金属间化合物Ni5Zn21和NiZn3,并形成了Ni-Zn固溶层。这些层的演化与温度有关。测定了反应温度和反应时间对界面反应层厚度的影响。讨论了界面层的生长行为和相互作用的活化能。发现反应机理随反应温度的变化而变化。
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The kinetics of interfacial interaction between eutectic Sn9Zn solder and nickel plating
The interfacial interaction between liquid eutectic Sn9Zn solder and electroplated Ni layer was investigated in the temperatures range of 230 ∼ 290°C. The interaction gives rise to various Ni-Zn intermetallic compounds, Ni5Zn21 and NiZn3, and Ni-Zn solid solution layer. The evolution of these layers is temperature dependent. The thickness of the interfacial reaction layer was measured with respect to reaction temperature and reaction time. The growth behavior of the interfacial layer and the activation energy of the interaction were discussed. The reaction mechanism was found to vary with respect to reaction temperature.
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