Silika Gel Termodifikasi Dimetilamin Sebagai Penyerap Anion Fosfat

Delfitri Delfitri, Budhi Oktavia, D. Kurniawati, Umar Kalmar Nizar
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Abstract

— Silica gel is one type of dry silica gel which is widely used as an adsorbent. Silica has the ability to absorbsi because it has two active site groups that can be activated, namely a silanol group and a siloxane group. This modification was carried out to increase the ability of silica to absorbsi ions, one of which was phosphate anion. In waters, very high levels of phosphate anion can disrupt the marine biota ecosystem because it can cause eutrophication or decreased oxygen levels that enter the waters. The modifier compound used is dimethylamine (DMA). Silica and dimethylamine can bind to several linking compounds, namely glycidopropyltrimethoxylan (gptms). The modified silica was characterized by FTIR and the absorption results were analyzed using a UV-Vis spectrophotometer. The results of the comparison of the absorption capacity of phosphate anions after modification are greater than before modification, where the absorption capacity of silica before modification is 1,2601 mg/g with an absorption percentage of 54,46% and silica after modification is 1.9686 mg/g with an absorption percentage of 1,9686 mg/g. 85,08%.
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修饰过的二氧化硅凝胶被甲醛吸收
-硅胶是一种干硅胶,广泛用作吸附剂。二氧化硅具有吸收硅的能力,是因为它有两个可以被激活的活性位基,即硅醇基和硅氧烷基。对二氧化硅进行改性是为了提高其对磷酸阴离子的吸收能力。在水中,非常高水平的磷酸盐阴离子会破坏海洋生物群生态系统,因为它会导致富营养化或降低进入水中的氧气水平。所使用的改性化合物是二甲胺(DMA)。二氧化硅和二甲胺可以结合到几种连接化合物,即甘油丙基三甲氧基胺(gptms)。用红外光谱对改性二氧化硅进行了表征,并用紫外可见分光光度计对改性二氧化硅的吸收结果进行了分析。改性后的二氧化硅对磷酸阴离子的吸收容量比改性前的大,其中改性前的二氧化硅的吸收容量为1,2601 mg/g,吸收率为54.46%;改性后的二氧化硅的吸收容量为1.9686 mg/g,吸收率为1,9686 mg/g。85年,08%。
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