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Penentuan Energi Celah Pita (Band Gap) Nanopartikel ZnO/Au Hasil Ablasi Laser dalam Cairan 纳米粒子ZnO/Au纳米粒子利用液体中的激光器裂纹
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.118243
Mardiana Julita, Muhandis Shiddiq, Miftahul Khair
The synthesis of ZnO and ZnO/Au nanoparticles using the laser ablation method in liquid has been successfully carried out. Characterization of the optical properties of ZnO and ZnO/Au using a UV-Vis Spectrophotometer (Ocean Optic MAYA Pro 2000) which was measured in the wavelength range of 275 - 875 nm. The characterization results obtained are absorbance values and band gap values of ZnO and ZnO/Au nanoparticles. From this study, the absorbance values of ZnO nanoparticles were found at wavelengths of 330 and 335 nm. After obtaining the absorbance value, the band gap value was analyzed for ZnO and ZnO/Au nanoparticles, respectively, namely 3.23 eV and 3.17 eV. The decrease in the band gap value in ZnO is due to the presence of Au in ZnO nanoparticles which can replace one of the lattices in the ZnO crystal structure.
利用激光烧蚀法在液体中成功地合成了ZnO和ZnO/Au纳米颗粒。用Ocean Optic MAYA Pro 2000紫外可见分光光度计在275 ~ 875 nm波长范围内对ZnO和ZnO/Au的光学性质进行了表征。表征结果为ZnO和ZnO/Au纳米粒子的吸光度值和带隙值。研究结果表明,ZnO纳米粒子在330和335 nm波长处的吸光度值。在获得吸光度值后,对ZnO和ZnO/Au纳米粒子的带隙值分别进行了分析,分别为3.23 eV和3.17 eV。ZnO中带隙值的减小是由于Au在ZnO纳米颗粒中的存在取代了ZnO晶体结构中的一个晶格。
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引用次数: 0
Uji Kondisi Optimum Desorpsi Anion Fosfat pada Silika Mesopori Termodifikasi DMA (Dimethylamine) 测试中二甲胺中磷酸化苯胺的最佳脱氨状态。
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.118092
Hainunnisa Syafitriza, Budhi Oktavia, Hary Sanjaya, Hardeli Hardeli
Mesoporous silica is solid silica having a pore size of 2-50 nm. Silica modification is done to increase the ability of silica to absorb anions, one of which is phosphate anion. The modifier compound used is dimethylamine. Silica and dimethylamine can bind with the addition of a linking compound, namely GPTMS. This modified silica can be used to adsorb phosphate anions to see the absorption of silica against phosphate anions. Phosphate ion adsorption using silica has an adsorption capacity of 0.0172 mg/g with an absorption percentage of 88.09%. Desorption with hydrochloric acid obtained a desorbed phosphate concentration of 0.773 mg/L with a desorption percentage of 89.02% while using sulfuric acid the desorbed phosphate concentration was 0.437 mg/L with a desorption percentage of 48.81%. The concentration variations of hydrochloric acid were 0.010 M, 0.025 M, 0.050 M, 0.075 M, 0.10 M, 0.15 M and 0.20 M. The maximum desorption result at 0.1 M concentration was 0.0086 mg with a percentage of 100%.
介孔二氧化硅是具有2- 50nm孔径的固体二氧化硅。对二氧化硅进行改性是为了提高二氧化硅对阴离子的吸附能力,其中一种阴离子是磷酸阴离子。所使用的改性化合物是二甲胺。二氧化硅和二甲胺可以通过添加一种连接化合物即GPTMS结合。将改性后的二氧化硅用于吸附磷酸阴离子,观察二氧化硅对磷酸阴离子的吸附效果。二氧化硅吸附磷酸盐离子的吸附量为0.0172 mg/g,吸附率为88.09%。盐酸解吸得到的解吸磷酸盐浓度为0.773 mg/L,解吸率为89.02%;硫酸解吸得到的解吸磷酸盐浓度为0.437 mg/L,解吸率为48.81%。盐酸浓度变化为0.010 M、0.025 M、0.050 M、0.075 M、0.10 M、0.15 M和0.20 M, 0.1 M浓度下最大解吸量为0.0086 mg,解吸率为100%。
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引用次数: 0
Pengaruh Jenis Aktivator Terhadap Penyerapan Ion Logam Pb2+Oleh Kulit Buah Matoa (Pometia pinnata) 活化剂类型对马托亚果皮吸附 Pb2+ 金属离子的影响
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.117006
Geita Yulyan Firel, Edi Nasra, Indang Dewata, Umar Kalmar Nizar
The effect of activation types on the biosorpsion of pb 2+ metal ions by matoa peel ( Pometia pinnata ) has been done. The purpose of this study was focused on the effect of the type of activator on the biosorpsion of pb 2+ metal ions by the matoa peel ( Pometia pinnata ) with chemical activation to determine the technical and condition of the activator according to the matoa peel which can be used as a Pb 2+ ion biosorbent. The method used is the batch method. The variables in this study were the type of activator and were characterized using the FTIR and AAS. The results showed that 0.1 M HCl was the best activator characterized by a decrease in % T of functional groups -OH, -CH and C-O which played an important role in the biosorption process, had the best Pb 2+ metal biosorption capacity obtained from the AAS results, namely of 0.6462 mg/g with % biosorption 80.6239%.
研究了不同活化类型对番茄皮吸附pb +金属离子的影响。研究了不同类型活化剂对化学活化的番茄皮对pb +金属离子的生物吸附效果的影响,并根据番茄皮对pb +离子的生物吸附性能确定了活化剂的工艺条件。所使用的方法是批处理方法。本研究的变量是活化剂的类型,并使用FTIR和AAS进行了表征。结果表明,0.1 M HCl为最佳活化剂,其特征是在生物吸附过程中起重要作用的官能团-OH、-CH和C-O的% T降低,AAS结果显示其对Pb 2+金属的最佳生物吸附量为0.6462 mg/g, %生物吸附量为80.6239%。
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引用次数: 0
Pengaruh Massa Adsorben Pada Biosorpsi Ion Logam Cr(VI) Menggunakan Biosorben Selulosa Dari Kulit Durian (Durio zibethinus L.) 榴莲皮纤维素生物吸附剂的吸附剂质量对金属六价铬离子生物吸附的影响
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.118351
Roza Herlina, Edi Nasra, Rahadian Zainul, Trisna Kumala Sari
The metal ion Cr(VI) is a very toxic substance with high solubility so that it can cause pollution to the environment. If the concentration of metal ions Cr(VI) exceeds the limit of 0.5 mg/L can damage ecosystems, the environment, poison living organisms and humans, then a method is needed to overcome the pollution caused by chromium waste. Biosorption is an effective and efficient method. The purpose of this study was to determine the optimum conditions for the absorption and absorption capacity of Cr(VI) metal ions. metal ion Cr(VI) with dihenylcarbazide and H 2 SO 4 will form a purple complex reaction. The maximum wavelength of Cr(VI) ion absorption was obtained at 543 nm. These results obtained optimum absorption conditions at an adsorbent mass of 0.6 grams with an absorption capacity of 12.7506 mg/g.
金属离子Cr(VI)是一种高溶解度的剧毒物质,对环境造成污染。如果金属离子Cr(VI)的浓度超过0.5 mg/L的限制,就会破坏生态系统、环境、毒害生物和人类,那么就需要一种方法来克服铬废物造成的污染。生物吸附法是一种有效的方法。本研究的目的是确定吸附Cr(VI)金属离子的最佳条件和吸附量。金属离子Cr(VI)与二苯基脲和h2so4形成紫色络合反应。对Cr(VI)离子的最大吸收波长为543 nm。结果表明,吸附剂质量为0.6 g,吸附量为12.7506 mg/g时吸附效果最佳。
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引用次数: 0
Degradasi Zat Warna Indigosol Red Ir Menggunakan Metode Sonolisis Dengan Bantuan Katalis ZnO 红色染料的降解使用了Sonolisis的方法在催化剂ZnO的帮助下
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.117679
Indah Humaira Saragih, Hary Sanjaya
This research was conducted for the modeling degradation process of Indigosol Red Ir dye using the sonolysis method with the help of a ZnO catalyst. This study aims to determine the optimum mass addition of ZnO catalyst in the degradation process of Indigosol Red Ir dye. Sonolysis method using an ultrasound with frequency 47 kHz. The results of the percent degradation were seen from the absorbance measurement using a uv-vis spectrophotometer at a maximum wavelength of 510.2 nm. The results showed that the addition of the optimum mass of ZnO catalyst was 0.05 grams with a degradation percentage of 93.72%.
本研究在ZnO催化剂的帮助下,采用声溶法模拟靛蓝溶胶红Ir染料的降解过程。本研究旨在确定氧化锌催化剂在靛蓝红Ir染料降解过程中的最佳质量添加量。使用频率为47千赫的超声波的声溶方法。用紫外-可见分光光度计在最大波长为510.2 nm处测定了降解率。结果表明,ZnO催化剂的最佳质量为0.05 g,降解率为93.72%。
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引用次数: 0
Analisis Proksimat Karbon Bonggol Pisang Kepok (Musa paradisiaca L) di Kecamatan Koto Tangah sebagai Sumber Karbon untuk Material Maju 作为先进材料碳源的 Koto Tangah 地区 Kepok 香蕉(Musa paradisiaca L)树皮的碳近似物分析
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.117504
Vionisa Vionisa, Umar Kalmar Nizar
Actived carbon can be produced from biomass waste containing starch, lignin, cellulose, and hemicellulose as a source for advanced materials. The purpose of this research is to analyze and determine the optimum temperature of the banana hump to obtain high quality, economical, and enviromentally friendly carbon. The method used for the manufacture of carbon from banana humps is by calcining in a furnace with a temperature 250°C-450°C for 1 hour. Proximate analysis of banana hump carbon used SNI 06-3730-1995 was performed by testing ash content, vapor content, and bound carbon. Based on the result obtained, the carbon of banana humpwith a carbonization temperature variation of 250°C is the optimum reaction with an ash content value of 20,26%, a vapor conten of 1,78%, and a bound carbon content of 77,96%.
活性炭可以从含有淀粉、木质素、纤维素和半纤维素的生物质废料中生产,作为先进材料的来源。本研究的目的是分析和确定香蕉驼峰的最佳温度,以获得优质、经济、环保的碳。从香蕉驼峰中制造碳的方法是在温度为250°C-450°C的炉子中煅烧1小时。采用SNI 06-3730-1995对香蕉驼峰碳进行了近似分析,测试了灰分含量、蒸汽含量和束缚碳。在炭化温度为250℃的条件下,香蕉驼峰炭的最佳反应为灰分值为20.26%,水蒸气含量为1.78%,结合碳含量为77.96%。
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引用次数: 0
Pengaruh pH dan Konsentrasi Terhadap Penyerapan Ion Logam Pb2+ Menggunakan Kulit Buah Matoa (Pometia pinnata) pH值和浓度作用Pb2+金属离子吸收的影响,使用Matoa果皮(Pometia pinnata)
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.117509
Deva Indriyani, Edi Nasra, Budhi Oktavia, Hesty Parbuntari, Desy Kurniawati
This research study was to determine the optimum conditions for the absorption of Pb2+ metal ions using the matoa fruit peel (Pometia pinnata) using the batch method with variations in pH, concentration, particle size, contact time and stirring speed. The results of the study showed that the optimum conditions for the absorption of Pb2+ occurred at pH 5, a concentration of 300 ppm with an absorption capacity of 34.015 mg/g. Pb2+ metal adsorption isotherm with matoa skin biosorbent (Pometia pinnata) tends to follow the Freundlich isotherm equation with a determinant coefficient (R) of 1. Keywords : Biosorption, Pb 2+ metal, Pometia pinnata , Batch method
本研究通过pH、浓度、粒径、接触时间和搅拌速度的变化,确定了番茄果皮吸附Pb2+金属离子的最佳工艺条件。研究结果表明,吸附Pb2+的最佳条件是pH为5,浓度为300 ppm,吸附量为34.015 mg/g。番茄皮生物吸附剂(Pometia pinnata)对Pb2+金属的吸附等温线符合Freundlich等温线方程,其决定系数(R)为1。关键词:生物吸附,Pb +金属,石榴,间歇法
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引用次数: 0
Penentuan Kondisi Optimum Desorpsi Anion Nitrat (NO3-) pada Silika Mesopori Termodifikasi Dimetilamina (DMA) 确定经内硅胶和二甲胺(DMA)的硝酸苯胺消化道(NO3-)的最佳降解条件
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.118091
Dipnorita Retno, Budhi Oktavia, Indang Dewata, Miftahul Khair
Mesoporous silica is an inorganic materials that has high potential to be applied in various industrial fields, one of its application is the adsorption method. To maximize the adsorption of mesoporous silica, modification of the silica surface was carried out with the addition of amine compounds. The amine compound used as a modifier is dimethylamine (DMA). Mesoporous silica which has been modified with dimethylamine is used in the nitrate anions adsorption process by the column method. The adsorption capacity of the nitrate anion is 0.0917 mg/g. After being adsorbed, the desorption process was carried out to release the adsorbed nitrate anions again. From the desorption process, it was found that HCl proved to be the best desorption agent used on nitrate anions. The optimum concentration of HCl was 0.15 M with the number of nitrate anions desorbed as much as 0.0459 mg with a 100% desorption percentage.
介孔二氧化硅是一种具有很高应用潜力的无机材料,其应用之一是吸附法。为了最大限度地提高介孔二氧化硅的吸附性能,对二氧化硅表面进行了胺类化合物的改性。用作改性剂的胺类化合物是二甲胺(DMA)。采用二甲胺改性的介孔二氧化硅用于柱法吸附硝酸盐阴离子。对硝酸盐阴离子的吸附量为0.0917 mg/g。吸附后进行解吸,将吸附后的硝酸盐阴离子再次释放。从解吸过程中发现,HCl是硝酸根阴离子的最佳解吸剂。HCl的最佳浓度为0.15 M,硝酸根负离子的解吸量可达0.0459 mg,解吸率为100%。
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引用次数: 0
Degradasi Zat Warna Rhodamin B menggunakan Katalis TiO2 dengan Metode Fotosonolisis 罗达敏B使用一种光合作用催化剂替其上色
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.118004
Wenti Aulia, Hary Sanjaya
Research has been carried out on the degradation of Rhodamine B dye with TiO2 as a catalyst using the photosonolysis method. The purpose of this study was to determine the optimum time and optimum mass of the TiO2 catalyst used to degrade rhodamine B. The results of the percentage degradation of rhodamine B were obtained from the absorbance value measured using a UV-Vis spectrophotometer. The maximum wavelength of rhodamine B obtained from the measurement of the UV-Vis spectrophotometer is 553.8 nm. The results showed that the optimum time to degrade rhodamine B was 210 minutes with a degradation percentage of 95.39%. On the effect of increasing the mass of TiO2 catalyst, the optimum mass of TiO2 is 0.05 grams with a degradation percentage of 93.44%.
以TiO2为催化剂,采用光声解法对罗丹明B染料进行了降解研究。本研究的目的是确定用于降解罗丹明B的TiO2催化剂的最佳时间和最佳质量,通过紫外-可见分光光度计测量的吸光度值得到罗丹明B的降解百分比。通过紫外可见分光光度计测量得到罗丹明B的最大波长为553.8 nm。结果表明,对罗丹明B的最佳降解时间为210 min,降解率为95.39%。在增加TiO2催化剂质量的影响下,TiO2的最佳质量为0.05 g,降解率为93.44%。
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引用次数: 0
Isolasi dan Karakterisasi α-Selulosa Dari Kulit Buah Matoa (Pometia pinnata) 果皮的孤立和α描述-Selulosa Matoa (Pometia pinnata)
Pub Date : 2023-08-01 DOI: 10.24036/periodic.v12i2.117793
Fauzan Aulia Akbar, Edi Nasra, Desy Kurniawati, Deski Beri, Hary Sanjaya
Cellulose isolation from the matoa fruit peel ( Pometia pinnata ) has been carried out by means of acid hydrolysis and alkaline hydrolysis. The purpose of this study was to isolate cellulose in the peel of matoa fruit and determine what is the purity level of cellulose contained in the peel of matoa fruit, FTIR is used to identify cellulose functional groups in matoa fruit peel. Results of this study, an yeild of the results of cellulose isolation of matoa peel was 41.3% with the purity level of cellulose of matoa fruit peel of 47.63%. The results of characterization using FTIR are known to have cellulose groups contained in the matoa peel such as -OH, -CH, and C-O groups which are the main functional groups in cellulose.
采用酸水解和碱水解两种方法对柚子果皮中的纤维素进行了分离。本研究的目的是分离出番茄果皮中的纤维素,确定番茄果皮中纤维素的纯度,并利用红外光谱对番茄果皮中的纤维素官能团进行鉴定。本研究的结果表明,番茄果皮纤维素分离率为41.3%,番茄果皮纤维素纯度为47.63%。利用FTIR表征的结果已知在西红柿皮中含有纤维素基团,如-OH、-CH和C-O基团,它们是纤维素中的主要官能团。
{"title":"Isolasi dan Karakterisasi α-Selulosa Dari Kulit Buah Matoa (Pometia pinnata)","authors":"Fauzan Aulia Akbar, Edi Nasra, Desy Kurniawati, Deski Beri, Hary Sanjaya","doi":"10.24036/periodic.v12i2.117793","DOIUrl":"https://doi.org/10.24036/periodic.v12i2.117793","url":null,"abstract":"Cellulose isolation from the matoa fruit peel ( Pometia pinnata ) has been carried out by means of acid hydrolysis and alkaline hydrolysis. The purpose of this study was to isolate cellulose in the peel of matoa fruit and determine what is the purity level of cellulose contained in the peel of matoa fruit, FTIR is used to identify cellulose functional groups in matoa fruit peel. Results of this study, an yeild of the results of cellulose isolation of matoa peel was 41.3% with the purity level of cellulose of matoa fruit peel of 47.63%. The results of characterization using FTIR are known to have cellulose groups contained in the matoa peel such as -OH, -CH, and C-O groups which are the main functional groups in cellulose.","PeriodicalId":213875,"journal":{"name":"Jurnal Periodic Jurusan Kimia UNP","volume":"35 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135055902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Jurnal Periodic Jurusan Kimia UNP
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