Hydrogen diffusion behavior in CH4N-molecularion-implanted wafers for three-dimensional stacked CMOS image sensors

Ryosuke Okuyama, T. Kadono, Ayumi Masada, Akihiro Suzuki, Koji Kobayashi, S. Shigematsu, R. Hirose, Yoshihiro Koga, K. Kurita
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Abstract

In this study, the diffusion behavior of hydrogen in a CH4N-molecular-ion-implanted epitaxial wafer was investegated by reaction kinetic analysis. Two hydrogen-trapping sites, carbon aggregate and end of range (EOR) defects, were formed in the CH4N-implanted region. The C-H2 binding state was formed in the carbon aggregate region. On the other hand, the N-H binding state was formed in the EOR defect region. This result indicates that CH4N-molecular-ion-implanted epitaxial wafers contribute to the reduction in Dit at the SiO2/Si interface due to hydrogen desorption from the CH4N-implanted region during heat treatment in the device process.
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三维堆叠CMOS图像传感器用ch4n分子注入晶圆中氢的扩散行为
本研究采用反应动力学分析方法研究了氢在ch4n分子离子注入外延片中的扩散行为。ch4n注入区形成了碳聚集体和EOR缺陷两个氢捕获点。碳聚集区形成C-H2结合态。另一方面,在提高采收率缺陷区形成了N-H结合态。这一结果表明,ch4n分子离子注入外延片有助于降低SiO2/Si界面上的Dit,这是由于在器件过程中热处理过程中ch4n注入区域的氢解吸所致。
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