The thermal stability of zirconium aluminate high-k film on strained SiGe layer

Z. Di, Miao Zhang, Weili Liu, S. Luo, Z. An, Zhengxuan Zhang, Zhitang Song, Chenglu Lin
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Abstract

Zr/sub 0.6/Al/sub 0.4/O/sub 1.8/ dielectric films were deposited directly on strained SiGe substrate at room temperature by ultra-high vacuum electron-beam evaporation (UHV-EBE) and then annealed in N/sub 2/ under various temperatures. X-ray diffraction (XRD) reveals that the onset crystallization temperature of the Zr/sub 0.6/Al/sub 0.4/O/sub 1.8/ film is about 900/spl deg/C, 400/spl deg/C higher than that of pure ZrO/sub 2/. The amorphous Zr/sub 0.6/Al/sub 0.4/O/sub 1.8/ film with a physical thickness of /spl sim/ 12 nm and an amorphous interfacial layer (IL) with a physical thickness of /spl sim/3 nm have been observed by high-resolution transmission electron microscopy (HRTEM). In addition, it is demonstrated there is no undesirable amorphous phase separation during annealing at temperatures below and equal to 800/spl deg/C in the Zr/sub 0.6/Al/sub 0.4/O/sub 1.8/ film. X-ray photoelectron spectroscopy (XPS) reveals that zirconium and aluminum are both in the fully oxidation states.
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铝酸锆高k薄膜在应变SiGe层上的热稳定性
采用超高真空电子束蒸发法(UHV-EBE)在应变SiGe衬底上直接沉积Zr/sub 0.6/Al/sub 0.4/O/sub 1.8/介质薄膜,然后在N/sub 2/中进行不同温度退火。x射线衍射(XRD)结果表明,Zr/sub 0.6/Al/sub 0.4/O/sub 1.8/薄膜的起晶温度约为900/spl℃,比纯ZrO/sub 2/薄膜的起晶温度高400/spl℃。通过高分辨率透射电镜(HRTEM)观察到物理厚度为/spl sim/ 12 nm的非晶态Zr/sub 0.6/Al/sub 0.4/O/sub 1.8/薄膜和物理厚度为/spl sim/3 nm的非晶态界面层(IL)。结果表明,Zr/sub 0.6/Al/sub 0.4/O/sub 1.8/薄膜在低于或等于800/spl℃的退火过程中没有出现不良的非晶态相分离现象。x射线光电子能谱(XPS)显示,锆和铝均处于完全氧化态。
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