Pengaruh Penambahan Titanium Dioksida (TiO2) terhadap Sifat Konduktor dari Polianilin (PANI)

S. Wulandari, Umar Kalmar Nizar
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Abstract

— This study aims to determine the effect of the addition of TiO 2 dopant on the electrical conductivity of polyaniline synthesis using the photopolymerization method and characterization with Fourier Transform Infrared (FTIR) and Diffuse Reflectance UV-Vis (DR UV-Vis). Synthesis of polyaniline was carried out by mixing aniline monomer with Ethylene Glycole Dimetacrylate (EGDMA) as a crosslinker and Dimethoxy Phenylacetophenone (DMPP) as an initiator, and the addition of TiO 2 dopant as much as 0.006 g, 0.011 g, 0.016 g, 0.021 g and 0.026 g. The obtained PANI and PANI/TiO 2 were measured for electrical conductivity using the Four Point Probe (FPP). The result shows that the optimal electrical conductivity value was 12.60 × 10 -3 S/cm which was owned by PANI added with TiO 2 of 0.006 g.
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本研究旨在利用光聚合法和傅里叶变换红外(FTIR)和漫反射紫外-可见(DR UV-Vis)表征来确定添加tio2掺杂剂对聚苯胺合成电导率的影响。以苯胺单体为原料,以乙二醇二甲基丙烯酸酯(EGDMA)为交联剂,二甲氧基苯乙酮(DMPP)为引发剂,分别加入0.006 g、0.011 g、0.016 g、0.021 g和0.026 g的tio2掺杂剂,合成聚苯胺。用四点探针(FPP)测量得到的聚苯胺和聚苯胺/二氧化钛的电导率。结果表明,当tio2用量为0.006 g时,聚苯胺的最佳电导率为12.60 × 10 -3 S/cm。
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