Pengaruh Kecepatan Pengadukan dan Waktu Kontak Terhadap Penyerapan Fenol Menggunakan Adsorben C-SinamalKaliks[4]Resorsinarena Hasil Sintesis Limbah Minyak Kayu Manis (Cinnamomum burmanii)

Dewi Kristina, S. Etika, Edi Nasra, Budhi Oktavia
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Abstract

— Phenol is included in hazardous waste so that its presence in the environment needs to be controlled. Phenol contamined water can cause liver damage, diarrhea, dark urine, and red blood cell breakdown. To overcome this environmental problem, the adsorption method can be applied using synthesized compounds such as C-CinnamalCalix[4]Resorcinarene (CCCR). CCCR is a derivative of Calix[4]Resorcinarene which can act as a host for cations, anions, and neutral molecules. It has a unique shape that has an active group, which can form hydrogen bonding with phenol solution. The purpose of this study was to determine the optimum conditions with variation in stirring speeds of 50, 100, 150, 200, and 250 rpm and contact times of 45, 60, 75, 105, and 150 minutes. Phenol was analyzed using a UV-Vis spectrophotometer (Specord 210). Adsorption phenol with CCCR obtained optimum conditions at stirring speeds of 200 rpm with an adsorption capacity of 2.016 mg/g and contact times of 60 minutes with an adsorption capacity of 2.079 mg/g.
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用C-SinamalKaliks合成废肉桂废液所产生的冲积速度和接触时间的影响
-有害废物中含有苯酚,因此需要控制其在环境中的存在。被苯酚污染的水会导致肝损伤、腹泻、尿色变深和红细胞分解。为了克服这一环境问题,可以使用合成的化合物如C-CinnamalCalix[4]间苯二甲酸(CCCR)进行吸附。CCCR是杯状杯间苯二烯的衍生物,可以作为阳离子、阴离子和中性分子的宿主。它具有独特的形状,具有活性基团,可与苯酚溶液形成氢键。本研究的目的是确定搅拌速度为50、100、150、200和250 rpm,接触时间为45、60、75、105和150分钟时的最佳条件。用紫外可见分光光度计(Specord 210)分析苯酚。CCCR吸附苯酚的最佳条件为搅拌转速为200 rpm,吸附量为2.016 mg/g,接触时间为60 min,吸附量为2.079 mg/g。
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