Preparasi Poli Tanin Untuk Meningkatkan Efisiensi Dye-Sensitized Solar Cell (DSSC) Preparasi Poli Tanin untuk Meningkatkan Efisiensi Dye-Sensitized Solar Cell (DSSC)

Annisa Ade Putri, Hardeli Hardeli, Fajriah Azra, Minda Azhar
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Abstract

— DSSC ( Dye-Sensitized Solar Cell ) is a type of third-generation solar cell based on dye as a photon absorber that has been widely used. In this study, modifications were made to tannin dyes to increase double bonds. Modifications were also carried out on the semiconductor by means of TiO 2 -CuO doping. TiO 2 -CuO doping can reduce the energy gap thereby increasing the TiO 2 conductivity. The dyes were characterized using FTIR and GC-MS, while the TiO 2 -CuO doping was characterized using a UV-DRS Spectrophotometer. The results of FTIR characterization of poly tannin dyes have shown specific groups of polymerization of polytannin glutaraldehyde resin. The characterization of TiO 2 -CuO doping showed a decrease in the energy gap of 3,2 eV to 3,01 eV. The highest efficiency was produced at 90 minutes polymer time with a tannin monomer concentration of 0,4 M of 8,332%.
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染料敏化太阳能电池(dye - sensitized Solar Cell, DSSC)是一种基于染料作为光子吸收剂的第三代太阳能电池,已得到广泛应用。在本研究中,对单宁染料进行了改性以增加双键。用tio2 -CuO掺杂的方法对半导体进行了修饰。tio2 -CuO掺杂可以减小能隙,从而提高tio2的电导率。用FTIR和GC-MS对染料进行了表征,用UV-DRS对tio2 -CuO掺杂进行了表征。对聚单宁染料的FTIR表征结果显示了聚单宁戊二醛树脂的特定聚合基团。tio2 -CuO掺杂表征表明,tio2 -CuO掺杂能隙从3.2 eV减小到3.1 eV。当单宁单体浓度为0.4 M时,聚合时间为90分钟,效率为8,332%。
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