Electronic and optical properties of Bi3.25La0.75Ti3O12 and SrBi2-xNdxNb2O9 perovskite-type ferroelectric materials

Z. Hu, J. Chu
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Abstract

The phase transitions and the temperature dependent electronic properties of Bi3.25La0.75Ti3O12 (BLT) film have been studied by transmittance spectra from 80 to 480 K. Anomalies of the optical constants are observed at 160 K and 300 K, which can be ascribed to the phase transitions. The optical properties of SrBi2-xNdxNb2O9 (SBNN) ceramics with the Nd concentrations from 0 to 0.2 have been investigated by Raman scattering spectra and spectroscopic ellipsometry. It can be found that the lattice vibrations slightly depend on the Nd concentrations. Moreover, the optical band gap linearly increases with the Nd concentrations due to charge compensation by the Nd doping.
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Bi3.25La0.75Ti3O12和SrBi2-xNdxNb2O9钙钛矿型铁电材料的电子和光学性质
利用80 ~ 480 K透射光谱研究了Bi3.25La0.75Ti3O12 (BLT)薄膜的相变和温度相关的电子特性。在160 K和300 K时观察到光学常数的异常,这可以归因于相变。利用拉曼散射光谱和椭圆偏振光谱研究了Nd浓度为0 ~ 0.2的SrBi2-xNdxNb2O9 (SBNN)陶瓷的光学性质。可以发现,晶格振动与Nd浓度有轻微的关系。此外,由于Nd掺杂的电荷补偿,光学带隙随Nd浓度线性增加。
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