Glow of own defects in ZnO polycrystals

N. Aluker
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Abstract

The photoluminescence of ZnO powders at room temperature upon excitation by microsecond pulses from the region of interband transitions and the region of exciton absorption has been studied. In the luminescence spectra, two regions characteristic of ZnO are observed: a short-wavelength region associated in the literature with exciton luminescence, and a long-wavelength region due to the presence of growth structural and impurity defects. The observed long-wavelength glow is divided into components with different glow durations, and several components that form this glow are identified. Experimental results and an analysis of the energy of formation and survival of the main structural defects make it possible to explain the luminescence of ZnO with allowance for the participation of only defects in the anionic sublattice and excitons in the process.
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ZnO多晶自身缺陷的发光
研究了ZnO粉体在室温下在微秒脉冲激发下,在带间跃迁区和激子吸收区产生的光致发光现象。在发光光谱中,观察到ZnO的两个特征区域:文献中与激子发光相关的短波长区域,以及由于存在生长结构和杂质缺陷而导致的长波长区域。将观测到的长波辉光分成具有不同辉光持续时间的组分,并确定了形成这种辉光的几种组分。实验结果和对主要结构缺陷形成和存活能量的分析,使得在考虑阴离子亚晶格缺陷和激子参与的情况下,可以解释ZnO的发光。
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