Study of the structure of SiAlON obtained by synthesis with low-temperature plasma energy

V. Vlasov, A. Klopotov, K. Bezukhov, N. Golobokov, M. Syrtanov, G. Volokitin
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Abstract

This article presents the results of studies of the effect of low-temperature plasma on a sample prepared from powders Si 3 N, AlN, urea solution and liquid glass. X-ray phase analysis established, that the use of plasma chemical synthesis produced the phase β-SiAlON compositions Si 5 AlON 7 with hexagonal system (Pearson symbol hP14, space group P6 3 /m. The diffractograms also show an X-ray amorphous phase and traces of initial compounds. A diagram showing the physical and chemical processes occurring during the interaction of the plasma flux with components in plasma chemical synthesis is presented.
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低温等离子体能量合成SiAlON的结构研究
本文介绍了低温等离子体对氮化硅粉、氮化铝粉、尿素溶液和液态玻璃制备样品的影响。x射线相分析确定,采用等离子体化学合成法制备相β-SiAlON的组分Si 5 AlON 7具有六边形体系(Pearson符号hP14,空间群P6 3 /m)。衍射图也显示出x射线非晶相和初始化合物的痕迹。给出了等离子体化学合成中等离子体通量与组分相互作用过程的物理化学过程示意图。
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