Cleaning in electronics: Understanding today's needs

P. Duchi, Anne-Marie Laügt, Marie Verdier
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Abstract

Because of the phase out of CFC's and HCFC's, standard solder pastes and fluxes evolved from RA and RMA fluxes, to No-Clean, low residue No-Clean, and very low residue No-Clean. Many companies came out with their cleaning solutions, aqueous and semi-aqueous, with each product release being more innovative than the previous one. Unfortunately for most of the suppliers of cleaners, two other trends appeared; lead-free soldering and the progressive miniaturization of electronic devices. Traditional chemicals like CFC's, HCFC's, brominated solvents, detergents and glycols cannot do a good cleaning job anymore because most flux formulations have changed. Also, assembly processes have been modified due to smaller components and more compact board assemblies. The world is composed of two main things: organics and inorganics. Organics are made of resins and activators, whereas inorganics are made of salts, metallic salts and fillers. Cleaning performance is affected by three main criteria. The first involves the Hansen Parameters which is a characterization of a contaminant to be dissolved and can be simplified by the solvency power of a product also known as the Kauri Butanol Index (KB Index). The second is surface tension, expressed in mN/m. This parameter must be considered because when the cleaning product cannot make contact with the contaminants under or around components, the contaminants cannot be dissolved. The third criteria are the physical parameters like temperature, mechanical activities, and the process cyle. The mastery to manage all of these parameters while facing high-tech miniaturization and environmental regulations, like ROHS, REACH, etc. brings innovation to cleaning in this electronic world.
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电子清洁:了解当今的需求
由于CFC和HCFC的逐步淘汰,标准焊锡膏和助焊剂从RA和RMA助焊剂发展到No-Clean,低残留No-Clean和极低残留No-Clean。许多公司推出了他们的清洁解决方案,水性和半水性的,每一个产品的发布都比前一个更具创新性。不幸的是,对大多数清洁剂供应商来说,出现了另外两种趋势;无铅焊接和电子设备的逐步小型化。传统的化学物质,如氯氟烃、氢氯氟烃、溴化溶剂、洗涤剂和乙二醇已经不能很好地清洁了,因为大多数助焊剂的配方已经改变了。此外,由于更小的组件和更紧凑的板组件,组装过程已被修改。世界主要由两种物质组成:有机物和无机物。有机物是由树脂和活化剂构成的,而无机物是由盐、金属盐和填料构成的。清洁性能受三个主要标准的影响。第一个涉及汉森参数,它是要溶解的污染物的特征,可以通过产品的溶解能力来简化,也称为贝壳杉丁醇指数(KB指数)。二是表面张力,单位为mN/m。必须考虑这个参数,因为当清洁产品不能接触组件下面或周围的污染物时,污染物不能溶解。第三个标准是物理参数,如温度、机械活动和工艺周期。在面对高科技小型化和环保法规(如ROHS, REACH等)的同时,掌握所有这些参数,为这个电子世界的清洁带来了创新。
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