A SiGe strain layer for gettering Fe in SIMOX

G. Campisi, P. Thompson, M. Anc, B. Cordts, D. Ioannou
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Abstract

Device processing introduces metallic contaminants that result in a reduction of device yields and reliability as well as higher gate oxide failure rates. Fortunately, these contaminants can be removed or neutralized at gettering sites associated with bulk oxygen precipitates and backside defects formed by a doped polysilicon layer. The problem with SIMOX, on the other hand, is the gettering sites are isolated by the buried oxide and additional metals can be introduced during O/sup +/ ion implantation and high temperature annealing. Here, we describe a new gettering process; the removal of metal contaminants from SIMOX using an MBE epitaxial SiGe alloy strain layer grown on a SIMOX silicon film. A SiGe alloy, with the desired germanium concentration and layer thickness, provides a highly strained region that acts as a sink(getter) for metals. With thermal cycling metals diffuse to or are driven into the surface strain layer for later removal. To demonstrate this effect and test the SiGe gettering strain layer effectiveness in SIMOX, we introduced a source of Fe/sup 54/ by implantation which is then diffused into the strain layer with an anneal. We analyzed the resulting material using TXRS (low angle surface reflection total X-ray fluorescence analysis), SIMS (Secondary Ion Mass Spectroscopy), and DLTS (Deep Level Transient Spectroscopy) measured on backgate on n-FET.<>
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SIMOX中Fe的SiGe应变层
设备加工引入金属污染物,导致设备产量和可靠性降低,以及更高的栅极氧化物故障率。幸运的是,这些污染物可以在与大块氧沉淀和由掺杂多晶硅层形成的背面缺陷相关的捕集点被去除或中和。另一方面,SIMOX的问题是,在O/sup +/离子注入和高温退火过程中,捕集点被埋藏的氧化物隔离,并且可以引入额外的金属。在这里,我们描述了一种新的捕集工艺;利用生长在SIMOX硅膜上的MBE外延SiGe合金应变层去除SIMOX中的金属污染物。具有所需锗浓度和层厚度的SiGe合金提供了一个高度应变的区域,作为金属的吸收(吸气)。随着热循环,金属扩散到或被驱动到表面应变层,以便以后去除。为了证明这种效果并测试SiGe在SIMOX中获得应变层的有效性,我们通过注入引入Fe/sup 54/源,然后通过退火将其扩散到应变层中。我们使用低角度表面反射全x射线荧光分析(TXRS)、二次离子质谱(SIMS)和深能级瞬态光谱(DLTS)在n-FET上的后门测量来分析所得材料。
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