Melt and flow behavior of Al into micron size features using incoherent radiation

A. Kamgar, R. C. Beairsto
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Abstract

Summary form only given. High-aspect-ratio via filling by rapid thermal melting of Al has been achieved, but with two major drawbacks. Pure or 0.5%-Cu-doped Al films 0.5- to 1.5- mu m thick were deposited on two types of wafer. Some wafers were patterned with 0.75- to 2- mu m-deep windows formed into deposited SiO while others have no topography. The Al films were deposited on 90-nm TiN or TiW layers. TiN, TiW or SiO/sub 2/ capping was used on some wafers. By melting Al deposited on several substrates the authors found that molten Al did not wet TiN. The Al balled up and pulled away from the surface. It seemed to wet W:Ti, however, along with a metallurgical reaction between Al, W, and Si resulting in the formation of several alloys of W and Al, as well as W:(Si,Al)/sub 2/. Although Al melts at 660 degrees C it did not flow until temperatures above 800 degrees C were achieved. However, even at these temperatures via-filling was not observed in 0.5- mu m-thick Al films. The authors found that Al thickness of 1 mu m or more was required for filling micron-size vias. The high temperature required for the Al flow which causes junction degradation and the agglomeration of Al film are two severe drawbacks for using the RTA technique in Al planarization.<>
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用非相干辐射研究铝在微米尺度下的熔化和流动行为
只提供摘要形式。通过快速热熔铝填充实现了高纵横比,但有两个主要缺点。在两种类型的晶圆上沉积了0.5- 1.5 μ m厚的纯或0.5% cu掺杂的Al薄膜。一些硅片上有0.75- 2 μ m深的窗口,形成沉积的SiO,而另一些硅片没有地形。Al薄膜被沉积在90 nm的TiN或TiW层上。在一些硅片上使用了TiN, TiW或SiO/sub / 2/封盖。通过熔化沉积在几种衬底上的Al,作者发现熔融Al不会润湿TiN。人工智能缩成一团,离开了水面。然而,随着Al、W和Si之间的冶金反应,它似乎湿润了W:Ti,从而形成了W和Al的几种合金,以及W:(Si,Al)/sub 2/。虽然铝在660摄氏度时熔化,但在达到800摄氏度以上的温度时才会流动。然而,即使在这些温度下,在0.5 μ m厚的铝膜中也没有观察到过充现象。作者发现,填充微米尺寸的孔需要1 μ m或更多的铝厚度。铝流动所需的高温导致结退化和铝膜的团聚是使用RTA技术进行铝平面化的两个严重缺陷
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