Efektivitas Penggunaan Al(OH)3 Sebagai Coprecipitant Pada Analisa Besi (Fe2+)

Dela Gustika, Edi Nasra
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Abstract

The concentration of metals in the water is generally very small, so it is difficult to determine by AAS. For this reason, before measuring with AAS, it is necessary to do pretreatment. One of the pretreatment that are commonly used to determine metal concentrations at low concentrations is coprecipitation, where this method is one of the pre-concentration methods. Preconcentration is a concentration technique used when the available sample has a very low concentration. There are several methods of preconcentration, one of which is the coprecipitation method. In this study, the coprecipitation method was used to analyze the metal content of Fe2+ in very small concentrations which would later be measured using an atomic absorption spectrophotometer. The purpose of this study was to determine the optimum conditions of coprecipitation of Fe2+ metal ions using Al(OH)3 as coprecipitant. The result obtained in this study were, the optimum conditions for Fe2+ metal ion coprecipitations occured at pH 9, Al3+ concentration 0,2 M, and the long deposition time occurred at 15 hours.
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Al(OH)3用于铁分析的合成物(Fe2+)的有效性
水中金属的浓度一般都很小,所以用原子吸收光谱法测定比较困难。因此,在原子吸收光谱法测定之前,有必要进行预处理。通常用于测定低浓度金属浓度的预处理方法之一是共沉淀法,该方法是预富集方法之一。预浓缩是一种在可用样品浓度很低时使用的浓缩技术。预富集有几种方法,其中一种是共沉淀法。在本研究中,共沉淀法用于分析非常小浓度的Fe2+的金属含量,然后使用原子吸收分光光度计测量。本研究的目的是确定以Al(OH)3为共沉淀剂的Fe2+金属离子共沉淀的最佳条件。本研究得到的结果是,Fe2+金属离子共沉淀的最佳条件是pH为9,Al3+浓度为0.2 M,沉淀时间为15小时。
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