Effective control of flat-band voltage in HfO2 gate dielectric with La2O3 incorporation

K. Okamoto, M. Adachi, K. Kakushima, P. Ahmet, N. Sugii, K. Tsutsui, T. Hattori, H. Iwai
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引用次数: 10

Abstract

The origin of negative flat-band shift using La2O3 incorporation in HfO2 dielectrics has been extensively examined. From careful extraction of effective work function of gate electrode and fixed charges at each interface, it has been revealed that La2O3 at high-k/Si substrate or high-k/SiO2 interface has either large amount of positive fixed charges or an additional dipole of 0.36 V compared to that of HfO2/Si or HfO2/SiO2. Stacked MOSCAPs were fabricated and the C-V characteristics show that flat-band voltage shift is mainly determined by high-k film which is in contact to Si or SiO2. Using HfLaO with different La concentration, the amount of shift in flat-band voltage could be well controlled, which might be due to the diffusion or pile-up of La atoms to the interface over 420degC. This study provides further insights in controlling the threshold voltage of HfO2 based oxides.
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La2O3掺入对HfO2栅极介质平带电压的有效控制
利用La2O3掺入HfO2电介质引起负平带位移的来源已被广泛研究。通过对栅极有效功函数和各界面固定电荷的仔细提取,发现与HfO2/Si或HfO2/SiO2相比,高k/Si衬底或高k/SiO2界面的La2O3具有大量的正固定电荷或额外的偶极子0.36 V。叠层MOSCAPs的C-V特性表明,其平带电压位移主要由接触Si或SiO2的高k薄膜决定。使用不同La浓度的HfLaO,可以很好地控制平带电压的位移量,这可能是由于La原子在420℃以上向界面扩散或堆积造成的。该研究为控制HfO2基氧化物的阈值电压提供了进一步的见解。
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