Controllable N-type Doping In Ultra-Wide Bandgap AlN By Chemical Potential Control

P. Bagheri, Cristyan Quiñones-García, P. Reddy, S. Mita, R. Collazo, Z. Sitar
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Abstract

High mobility of 270 cm2/Vs and free electron concentration as high as 1015 cm-3 were achieved in Si doped AlN grown on AlN single crystal via point defect management. CN incorporation in homoepitaxial film was successfully reduced by increasing the V/III and growth temperature as two growth knobs during the MOCVD growth. This work demonstrates the Si doping limit in AlN as low as mid-1017 cm-3 via Chemical Potential Control during the deposition process. CN and threading dislocations are two acceptor-type compensators determining the low doping limit in n-type AlN. Suppression of these defects to further improve the low doping limit (minimum achievable carrier concentration along with the maximum mobility) opens up pathways for realization of AlN-based power electronic devices.
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化学势控制超宽禁带氮化铝中可控n型掺杂
通过点缺陷管理,在AlN单晶上生长的掺硅AlN获得了270 cm2/Vs的高迁移率和1015 cm-3的自由电子浓度。在MOCVD生长过程中,通过提高V/III和生长温度,成功地减少了CN在同外延膜中的掺入。在沉积过程中,通过化学势控制证明了Si在AlN中的掺杂极限低至1017 cm-3中。CN和螺纹位错是决定n型AlN低掺杂极限的两种受体型补偿器。抑制这些缺陷,进一步提高低掺杂极限(最小载流子浓度和最大迁移率),为实现基于aln的电力电子器件开辟了途径。
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