Comparison of two methods of improving the characteristics of a double-color white organic light-emitting diode

Xue Chen, Wenqing Zhu, Sai-na Wang, F. Xu, Hong Xu, Xiao-Wen Zhang, Xifeng Li, Xueyin Jiang, Zhilin Zhang
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Abstract

White organic light-emitting diode was realized by co-doping a blue dye p-di(p-N,N-diphenyl-amino-styryl)benzene(DSA-ph) and a red dye 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran(DCJTB) into a blue host 2-(t-butyl)-9,10-di(2-naphthyl)anthracene(TBADN), achieving a brightness of 11580 cd/m2 at 200 mA/cm2, and a maximum current efficiency of 7.53 cd/A. The improvement was due to efficiency energy transfer from host to guest by the aid of assistant energy transfer mechanism. The device introduced a (4,4'-N,N'-dicarbazole)biphenyl/4,4'-bis(N-carbazolyl)biphenyl(CBP) interlayer between separate double emissive layers with the same materials showed improved color stability, due to the blocking effect of the CBP layer, which contributed to stable and even exciton distribution in both blue and red emission layer.
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改进双色白光有机发光二极管特性的两种方法的比较
将蓝色染料p-二(p-N, n -二苯基-氨基苯基)苯(DSA-ph)和红色染料4-(二氰胺)-2-t-丁基-6-(1,1,7,7-四甲基julolidyl-9-烯基)- 4h -吡喃(DCJTB)共掺杂到蓝色主体2-(t-丁基)-9,10-二(2-萘基)蒽(TBADN)中,实现了白色有机发光二极管,在200 mA/cm2下亮度为11580 cd/m2,最大电流效率为7.53 cd/ a。这种改善是由于在辅助能量传递机制的帮助下,主客之间的能量传递效率提高。该装置在具有相同材料的独立双发射层之间引入(4,4'-N,N'-双咔唑)联苯/4,4'-双(N-咔唑)联苯(CBP)中间层,由于CBP层的阻挡作用,提高了颜色稳定性,有助于蓝、红发射层中激子分布稳定均匀。
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