Photoluminescence caused by presence of defects and oxides at the surface of Hg/sub 1-x/Cd/sub x/Te

M. Scepanovi, I. Hinić, M. Jevtic
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Abstract

The results of photoluminescence (PL) measurements performed for Hg/sub 1-x/Cd/sub x/Te (x=0.165) samples are presented. The surfaces of these samples were modified using long exposure to the atmosphere (series A), etching by 0.5% Br-methanol during 1 minute (series B) and during 5 minutes (series C). For each series samples PL spectra were measured at different temperatures in the range from 16 to 300 K. PL bands at about 2.1 eV and 2.3 eV are recognized in PL spectra of each series samples. The analysis of PL and Raman spectra shows that the band at /spl sim/2.1 eV is caused by presence of the nonstoichiometric oxides. The band at 2.3 eV originates of organic compounds which are deposited at the surface during etching process. PL of the observed samples decreases after irradiation by intense nanosecond pulse of Nd:YAG laser.
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Hg/sub - 1-x/Cd/sub -x/ Te表面存在缺陷和氧化物引起的光致发光
给出了汞/亚1-x/Cd/亚x/Te (x=0.165)样品的光致发光(PL)测量结果。这些样品的表面通过长时间暴露于大气(系列A),在1分钟(系列B)和5分钟(系列C)内用0.5% br -甲醇蚀刻来修饰。对于每个系列样品,在16至300 K的不同温度范围内测量了PL光谱。在每个系列样品的PL光谱中都可以识别出2.1 eV和2.3 eV左右的PL波段。发光光谱和拉曼光谱分析表明,在/spl sim/2.1 eV处的波段是由非化学计量氧化物的存在引起的。2.3 eV波段是蚀刻过程中沉积在表面的有机化合物。在强纳秒脉冲Nd:YAG激光的照射下,观察到的样品的PL值降低。
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