Fabrication of wearable strain sensor by using a novel hybrid Cu ink composed of bimodal Cu particle ink and Cu-based metal-organic decomposition ink

Cong Gan, Hai-Jun Huang, Bin Hou, Min-bo Zhou, Xin-Ping Zhang
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Abstract

In this work, bimodal Cu particles have been synthesized by using 2-amino-2-methyl-1-propanol (AMP)-based hybrid capping agent for the first time. A novel hybrid Cu ink is prepared by combining bimodal Cu particles with solvents and Cu-based metal-organic decomposition (MOD) ink composed of Cu(II) formate, AMP and octylamine. The printed Cu patterns (films) by using the hybrid Cu ink show resistivity as low as 60 μΩ•cm after sintering under mid processing conditions (e.g., sintering at 110°C for 20 min in nitrogen atmosphere). The results also show that sintered Cu films of the hybrid Cu ink have good adhesion property on glass, polyimide (PI) and polyethylene terephthalate (PET) substrates, and the flexible Cu circuits on flattening and bending PI or PET substrates play the function well, in terms of easily lighting LEDs (light emitting diodes) in the circuits. Finally, the wearable strain sensor fabricated by using the hybrid Cu ink can also be well used to monitor the movement of human finger. All these results show that the hybrid Cu ink has high potential for application in printed flexible electronics.
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由双峰铜颗粒油墨和铜基金属有机分解油墨组成的新型混合铜油墨制备可穿戴应变传感器
本文首次采用2-氨基-2-甲基-1-丙醇(AMP)基杂化封盖剂合成了双峰铜颗粒。将双峰态铜颗粒与溶剂结合,制备了一种新型的铜基金属有机分解(MOD)油墨,该油墨由甲酸铜、AMP和辛胺组成。在中等工艺条件下(例如,在氮气气氛中110℃烧结20 min),使用混合铜墨水打印的Cu图案(薄膜)在烧结后的电阻率低至60 μΩ•cm。结果还表明,混合Cu油墨的烧结Cu膜在玻璃、聚酰亚胺(PI)和聚对苯二甲酸乙二醇酯(PET)基板上具有良好的粘附性能,并且在PI或PET基板上的柔性Cu电路可以很好地发挥作用,易于点亮电路中的led(发光二极管)。最后,利用混合铜墨水制作的可穿戴应变传感器也可以很好地用于监测人体手指的运动。这些结果表明,混合铜油墨在印刷柔性电子领域具有很大的应用潜力。
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