Effect of two-step organic modification on sol-gel derived mesoporous silica films

Yumei Zhu, Jun Shen, Bin Zhou, Guang-ming Wu, Xingyuan Ni, Zhihua Zhang, Yuan Liu
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Abstract

A new way to modify the surface of mesoporous silica film to be hydrophobic is introduced in this paper. A surface modification agent Hexamethyldisilazane (HMDS) was applied to yield hydrophobic groups on the surface of porous silica films before and after template removal to prevent the absorption of moisture. Compared to the normal hydrophobic treatment, the hydrophobic properties of the mesoporous silica films were enhanced greatly after the two-step treatments.
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两步有机改性对溶胶-凝胶衍生介孔二氧化硅薄膜的影响
介绍了一种将介孔二氧化硅膜表面改性为疏水膜的新方法。采用表面改性剂六甲基二硅氧烷(HMDS)在多孔硅膜去除模板前后产生疏水性基团,以防止水分的吸收。与常规疏水处理相比,经过两步处理的介孔二氧化硅膜的疏水性能得到了很大的提高。
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