Lifetime Improvement Of Perovskite Solar Cell Using A Photoactive Phase Change Material

M. Alidaei, Vahid Ahmadi, Farzaneh Arabpour
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Abstract

The perovskite structure is decomposed to its precursor in the face of continuous light irradiation (mainly UV light), humidity, and heat. In this work, mesoporous PSCs are fabricated in uncontrolled environment. The UV light stability of the PSC is enhanced by adding a photoactive phase change material (PCM) into the perovskite. The PCM undergoes trans to cis isomerization under UV light irradiation. Then, the cis form absorbs the heat produced in the solar cell and converts it into its trans isomer in a reversible process. By this approach, the destructive effect of UV light and heat is prohibited, leading to the enhancement of PSC durability by more than 138 % compared to devices without PCM. It should be noted that there is no significant difference in the PCE of both solar cells.
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利用光活性相变材料改善钙钛矿太阳能电池寿命
钙钛矿结构在连续光照(主要是紫外光)、湿度和热量的作用下分解为其前驱体。在本研究中,介孔聚氯乙烯是在非受控环境下制备的。通过在钙钛矿中加入光活性相变材料(PCM),增强了PSC的紫外光稳定性。紫外光照射下PCM发生反式到顺式异构化。然后,顺式吸收太阳能电池中产生的热量,并在可逆过程中将其转化为反式异构体。通过这种方法,紫外光和热的破坏性影响被禁止,导致PSC的耐用性比没有PCM的设备提高138%以上。需要注意的是,两种太阳能电池的PCE没有显著差异。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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