FTIR and optical transmittance investigation of hydrophobic SiO2-Al2O3 composite films

Linlin Tian, L. Yao, Shuo Wang, Ruiqing Xu, Lin Li, X. Fang
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引用次数: 1

Abstract

The hydrophobic and transparent SiO2-Al2O3 composite films were prepared by the sol-gel process using tetraethoxysliane (TEOS) and aluminium isopropoxide Al(C3H7O)3 as precursors, methyltriethoxysilane (MTES) and cetyltrimethylammonium bromide (CTAB) as chemical modifier and surfactant respectively. Optimum condition for the SiO2-Al2O3 nano-composite films with hydrophobic and transparent as well as mechanical properties simultaneously is investigated. It was found that the Si/Al molar ratio should be 1:0.008 and the calcined temperature should be 300°C. The infrared spectra of the films indicated that the hydrophobic surface of the film was due by the introduction of the methyl groups.
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疏水性SiO2-Al2O3复合膜的红外光谱和光透过率研究
以四乙氧基硅烷(TEOS)和异丙铝铝(C3H7O)3为前驱体,甲基三乙氧基硅烷(MTES)和十六烷基三甲基溴化铵(CTAB)分别为化学改性剂和表面活性剂,采用溶胶-凝胶法制备了疏水透明SiO2-Al2O3复合薄膜。研究了制备具有疏水性、透明性和力学性能的SiO2-Al2O3纳米复合膜的最佳工艺条件。结果表明,硅铝摩尔比为1:0.0 . 8,煅烧温度为300℃。薄膜的红外光谱表明,薄膜的疏水表面是由甲基的引入引起的。
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