In situ AFM Study of the Electropolymerization of Polypyrrole/Gold Nanocomposite

Qin Zhou, Changming Li
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引用次数: 1

Abstract

In this work, an electrochemical cell was designed and fabricated for in situ AFM study of the electropolymerization process of PPY in the presence of gold nanoparticles. PPY/Au nanocomposite was one step-synthesized simply by the potentiostatic deposition at constant potential. Based on the results of the current-time transient (I-t) measurements and in situ AFM measurements, it was found that the nucleation and growth of PPY/Au nanocomposite was an instantaneous three-dimension progress after nuclei overlapping. Regarding the process before nuclei overlapping, compared with that of pure PPY, it departed from the instantaneous three-dimension progress because of the presence of gold nanoparticles.
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聚吡咯/金纳米复合材料电聚合的原位AFM研究
在本工作中,设计并制作了一个电化学电池,用于原位原子力显微镜研究聚吡啶在金纳米颗粒存在下的电聚合过程。采用恒电位沉积法一步合成了PPY/Au纳米复合材料。基于电流时间瞬态(I-t)测量和原位AFM测量结果,发现PPY/Au纳米复合材料的成核和生长是原子核重叠后的瞬时三维过程。在原子核重叠前的过程中,由于金纳米粒子的存在,与纯PPY相比,它偏离了瞬时三维过程。
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