Effect of rapid thermal annealing on Ti/Al-GaN contacts

Xue Li, Yong Kang, Xiangyang Li, H. Gong, Haxiong Fang
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Abstract

Non-intentionally-doped wurtzite GaN epitaxial layers used in this study were grown on (0001) sapphire by metal organic chemical vapour deposition technique. Ti/Al(24nm/90nm) contacts were deposited by ion beam sputtering. Effect of rapid thermal annealing on Ti/Al-GaN contacts was investigated by I-V measurements and AES depth profiles. Surface morphologies were characterized by AFM. Schottky barrier height and specific contact resistivity decreased at first and then increased as annealing temperature increased. The lowest specific contact resistivity was obtained at 600/spl deg/C, i.e.3.04 /spl times/ 10/sup -4//spl Omega//spl middot/cm/sup 2/. However, the ideality factors increased with increase of annealing temperatures. Auger depth profile analysis showed that Ti had diffused into annealed GaN samples, a heavily n-doped layer formed at Ti/GaN interface. The tunneling current mechanism played a role in increase of ideality factors after annealing. The changes of surface morphologies at different annealing temperatures were characterized by AFM. The root mean square roughness of the as-grown sample was 2.9/spl Aring/. After 600/spl deg/C annealing, the root mean square roughness increased to 41.5/spl Aring/. These results showed that thermal annealing-induced changes near the surface region of contacts were significant. The thermal stability of contacts needs further study. Ohmic contacts formed at 600/spl deg/C are due to lower barrier height and tunneling current transport.
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快速热退火对Ti/Al-GaN接触的影响
采用金属有机化学气相沉积技术在(0001)蓝宝石上生长了非故意掺杂的纤锌矿GaN外延层。采用离子束溅射沉积Ti/Al(24nm/90nm)触点。通过I-V测量和AES深度剖面研究了快速退火对Ti/Al-GaN触点的影响。表面形貌采用原子力显微镜进行表征。随着退火温度的升高,肖特基势垒高度和比接触电阻率先减小后增大。在600/spl℃时获得了最低的比接触电阻率,即3.04 /spl times/ 10/sup -4//spl Omega//spl middot/cm/sup 2/。而理想因子随退火温度的升高而增大。俄歇深度剖面分析表明,Ti扩散到退火后的GaN样品中,在Ti/GaN界面处形成了一层重氮掺杂层。退火后,隧道电流机制对理想因子的增加起作用。利用原子力显微镜对不同退火温度下表面形貌的变化进行了表征。生长样品的均方根粗糙度为2.9/spl / Aring/。600/spl℃退火后,均方根粗糙度提高到41.5/spl Aring/。这些结果表明,接触表面附近的热退火引起的变化是显著的。触点的热稳定性有待进一步研究。在600/spl度/C下形成的欧姆接触是由于较低的势垒高度和隧穿电流输运。
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