Adsorpsi Anion Nitrat Menggunakan Silika Gel (SiO2) GPTMS Dimodifikasi dengan Dimetilamina

Anisa Nahari, Budhi Oktavia, M. Khair, Ananda Putra
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Abstract

Silica or silicon dioxide is a chemical compound with the molecular formula SiO2 which can be obtained from the synthesis of crystals, silica minerals, and vegetables. Compounds resulting from the polymerization of silicic acid, which are composed of a tetrahedral SiO4 unit chain with the general formula SiO2. Each silica atom is surrounded by four oxygen atoms. Silica forms a polyhedral network, where the bonds between oxygen tetrahendral are one and the other. Silica will form a framework that has pores that are quite open and allow other molecules to enter and undergo adsorption on the surface of the silica. Modification of silica is done by adding heat at a certain temperature, adding reagents to the active site of silica will change the silica functional group. Silica with the addition of amine compounds reacted with GPTMS can be used as nitrate anion adsorption to see the absorption capacity of silica against nitrate anions using the batch method. The factors used to see this adsorption capacity include pH at pH 7 with an absorption of 1.931463 mg/g and the percentage of absorption is 79.5%. and contact time with a time of 90 minutes with an absorption of 0.32677 mg/g and the percentage of absorption is 67.28785%.
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硝酸阴离子的消化道使用二氧化硅改用二恶英修饰过的二恶英
二氧化硅或二氧化硅是一种分子式为SiO2的化合物,可以从合成晶体、二氧化硅矿物和蔬菜中获得。由硅酸聚合而成的化合物,由四面体SiO4单元链组成,通式为SiO2。每个硅原子被四个氧原子包围。二氧化硅形成一个多面体网络,其中氧四面体之间的键是一个和另一个。二氧化硅将形成一个具有相当开放的孔隙的框架,允许其他分子进入并在二氧化硅表面进行吸附。二氧化硅的改性是通过在一定温度下加温来完成的,在二氧化硅的活性位点加入试剂会改变二氧化硅的官能团。二氧化硅与胺类化合物的加入与GPTMS反应可作为硝酸盐阴离子的吸附,用批处理法观察二氧化硅对硝酸盐阴离子的吸附能力。考察吸附量的因素包括pH值为ph7时的吸附量为1.931463 mg/g,吸附率为79.5%。接触时间为90 min,吸收率为0.32677 mg/g,吸收率为67.28785%。
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