Nanocrystalline TiO/sub 2/ thin films for O/sub 2/ gas sensing

Y. Li, M. Atashbar, M. Ghantasala, W. Wlodarski, M. Austin
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Abstract

Titanium dioxide (TiO/sub 2/) thin films have been prepared using a nanosized TiO/sub 2/ suspension and a spin-coating process. The morphology, microstructure, crystalline structure and chemical composition of the TiO/sub 2/ thin films have been investigated using SEM, XRD, and RBS. SEM analysis showed that the films are smooth and uniform with an average particle size of 25 nm. The crystal structure of the films is a mixture of 70% anatase and 30% rutile phases. RBS characterisation has revealed that the film is sub-stoichiometric TiO/sub 2-n/. The variation of electrical resistance of the thin films has been examined at different oxygen concentrations from 1 ppm to 1%. The response of the sensor to 100 ppm, 1000 ppm, and 1% O/sub 2/ gas is 1.4, 2.4, and 4.9, respectively. The response and recovery times (t/sub 0.90%/) are about 2 minutes.
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用于O/sub /气体传感的纳米晶tio2 /sub /薄膜
采用纳米tio2 /sub - 2/悬浮液和旋涂法制备了二氧化钛(TiO/sub - 2/)薄膜。采用SEM、XRD和RBS等手段对tio2 /sub /薄膜的形貌、微观结构、晶体结构和化学成分进行了表征。SEM分析表明,薄膜光滑均匀,平均粒径为25 nm。薄膜的晶体结构为70%锐钛矿和30%金红石相的混合物。RBS表征表明该膜为亚化学计量TiO/sub - 2-n/。在1 ppm ~ 1%的不同氧浓度下,研究了薄膜电阻的变化。传感器对100 ppm、1000 ppm和1% O/sub 2/气体的响应分别为1.4、2.4和4.9。响应和恢复时间(t/sub 0.90%/)约为2分钟。
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