Influence of Fe3+ ion substitution on Structural, Magnetic Properties and Magnetoresistance Effect of Pr0.75Na0.05K0.20MnO3 System

Siti Sumaiyah Sheikh Abdul Aziz
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Abstract

The effects of partial substitution of Fe at the Mn site on structural, magnetic, and electrical properties of monovalent doped Pr0.75Na0.05K0.20Mn0.95Fe0.05O3 manganite prepared by the solid-state method were investigated. X-ray Diffractometer, AC Susceptibility, and four point probe measurements were used to characterize the structural, magnetic, and electrical properties. The sample crystallized in an orthorhombic structure with a Pnma space group. The sample exhibited ferromagnetic (FM) to paramagnetic (PM) transition behaviour with Curie Temperature, TC value of 121.5 K. From the Resistivity versus temperature analysis, the sample exhibited insulating behaviourover entire temperature from 30 K - 300 K. Fe substitution exhibited high magnetoresistance (MR %) value at low temperature region, indicating the extrinsic mechanism of MR effect.
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Fe3+离子取代对Pr0.75Na0.05K0.20MnO3体系结构、磁性能及磁阻效应的影响
研究了Fe在Mn位部分取代对固态法制备的一价掺杂Pr0.75Na0.05K0.20Mn0.95Fe0.05O3锰铁的结构、磁性和电学性能的影响。x射线衍射仪、交流磁化率和四点探针测量被用来表征结构、磁性和电学性质。样品结晶为具有Pnma空间群的正交结构。样品在居里温度为121.5 K时表现出铁磁(FM)向顺磁(PM)的转变行为。从电阻率-温度分析中,样品在30 K - 300 K的整个温度范围内表现出绝缘行为。铁取代在低温区表现出较高的磁阻(MR %)值,表明了磁阻效应的外在机制。
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