Preparation and Surface Modification of Nanocellulose and Its Adsorption Performance on Cu2+

Yantao Yang, Yuanna Li, Wenkai Yang, Xiunan Cui, Tingzhou Lei
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Abstract

Nanocellulose fibers (NCFs) were converted to cellulose nanocrystals (CNCs) and then modified with diethylenetriamine pentaacetic acid (DTPA) to form modified CNCs (DTPA–CNCs), which were investigated as adsorbents for removing Cu2+ from aqueous solution. The adsorption behavior was affected by pH, contact time, dosage and raw Cu2+ concentration. Langmuir model is the best method to fit the adsorption isotherm of experimental results. The optimal conditions for Cu2+ adsorption were 2 h at 35 °C and pH 3, the optimal adsorption capacity is 94.5 mg/g. These functional groups on the DTPA–CNCs provided enhanced adsorption capacity, compared with unmodified NCFs.
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纳米纤维素的制备、表面改性及其对 Cu2+ 的吸附性能
研究人员将纳米纤维素纤维(NCFs)转化为纤维素纳米晶体(CNCs),然后用二乙烯三胺五乙酸(DTPA)对其进行改性,形成改性 CNCs(DTPA-CNCs),并将其作为从水溶液中去除 Cu2+ 的吸附剂。吸附行为受 pH 值、接触时间、用量和原始 Cu2+ 浓度的影响。Langmuir 模型是拟合实验结果吸附等温线的最佳方法。Cu2+ 的最佳吸附条件为 35 °C、pH 值为 3、接触时间为 2 小时,最佳吸附容量为 94.5 mg/g。与未改性的 NCFs 相比,DTPA-CNCs 上的这些官能团增强了吸附能力。
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来源期刊
Journal of Biobased Materials and Bioenergy
Journal of Biobased Materials and Bioenergy 工程技术-材料科学:生物材料
自引率
0.00%
发文量
60
审稿时长
6 months
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