Effect of medium and pressure on stress corrosion cracking susceptibility of a nickel-based alloy

Zhenyu Chen, Zhongliang Zhu, Ju Liu, Peihan Li, Zhangyang Chen, Tianyi Zhang, Naiqiang Zhang
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Abstract

Nickel-based alloy Inconel 617 is a candidate material for advanced ultra-supercritical units. Stress corrosion cracking (SCC) susceptibility of Inconel 617 under low-pressure superheated steam (0.1 MPa), high-pressure superheated steam (8 MPa) and supercritical water (25 MPa) at 650 °C was studied through slow strain rate tensile tests at strain rate of 5 × 10−7 s−1. The results indicate that Inconel 617 is susceptible to SCC in both superheated steam and supercritical water, with susceptibility increasing with pressure. In a nitrogen atmosphere, fractures were predominantly transgranular ductile. The fracture surface featured dimples and micropores. In three corrosive environments, both intergranular and transgranular fractures were observed. The rock sugar-like morphology becomes more and more obvious as the pressure increases. A large number of cracks perpendicular to the loading axis were found on gauge surface. The SCC mechanism for Inconel 617 in superheated steam and supercritical water conditions is internal oxidation.
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介质和压力对镍基合金应力腐蚀开裂敏感性的影响
镍基合金 Inconel 617 是先进超超临界机组的候选材料。通过应变速率为 5 × 10-7 s-1 的慢应变拉伸试验,研究了 Inconel 617 在 650 °C 的低压过热蒸汽(0.1 MPa)、高压过热蒸汽(8 MPa)和超临界水(25 MPa)条件下的应力腐蚀开裂(SCC)敏感性。结果表明,Inconel 617 在过热蒸汽和超临界水中都很容易发生 SCC,而且易感性随压力的增加而增加。在氮气环境中,断口主要呈跨晶韧性。断口表面具有凹陷和微孔。在三种腐蚀环境中,均观察到晶间和跨晶断裂。随着压力的增加,岩糖状形态越来越明显。在量规表面发现了大量垂直于加载轴的裂纹。Inconel 617 在过热蒸汽和超临界水条件下的 SCC 机理是内部氧化。
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