Optical and Degradation Characteristics of Green Synthesized Cornstarch-Base Bioorganic Polymer

Marowa Yass, Ahmed Al-Haddad, Ali Jaafar Sadeq
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Abstract

Chemical-base polymers are mostly related to environmental pollution since their poisonous, non-biodegradable wastes, and negatively impact plants, animals, and people. In many locations where petroleum-based plastics are used, bioorganic polymers and biomaterials can play a promising role and are accepted. In one such attempt, glycerol was used as a natural plasticizer, and cornstarch was used to create bioorganic polymers and biocomposites. Resulting in a highly degradable bioorganic polymer in water and soil, display FE-SEM images of a BOP's top and cross-section views, flat surface and smooth, the inner structure of BOP does not demonstrate any bubbles, cracking, flipping, or splitting., estimate the optical band gap indirect of BOP of 3.69 eV that can absorb 96% of UV light and transmit 98 % of visible light. The FTIR assay detects the functional aggregates of the BOP as well as the presence of a hydrogen bond in the BOP matrix. Raman spectroscopy detection composition and scope distribution of the various components in a prepared BOP. The decay constants of BOP were gaged as 12.4 ± 1.8 and 3.49 ± 0.41 for the water and soil, respectively. The decay values show an acceptable variation due to the nature of the BOP on one side and the water and soil on the other side. These findings conclude diverse applications highlighting BOP as a candidate, e.g., UV screening or protective layer, food packaging, and replacing the chemical fertilizer with BOP agent to deliver the organic substances to the plants.
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绿色合成玉米淀粉基生物有机聚合物的光学特性和降解特性
化学基聚合物大多与环境污染有关,因为它们是有毒的、不可生物降解的废物,并对植物、动物和人类产生负面影响。在许多使用石油基塑料的地方,生物有机聚合物和生物材料可以发挥很好的作用,并被人们所接受。在一次尝试中,甘油被用作天然增塑剂,玉米淀粉被用来制造生物有机聚合物和生物复合材料。BOP 的顶视图和横截面图的 FE-SEM 图像显示,BOP 表面平整光滑,内部结构没有任何气泡、裂纹、翻转或分裂,估计 BOP 的光带隙间接为 3.69 eV,可吸收 96% 的紫外光,透过 98% 的可见光。傅立叶变换红外光谱检测 BOP 的功能聚集体以及 BOP 基质中是否存在氢键。拉曼光谱检测制备的 BOP 中各种成分的组成和范围分布。水和土壤中 BOP 的衰变常数分别为 12.4 ± 1.8 和 3.49 ± 0.41。由于一边是 BOP,另一边是水和土壤,衰变值显示了可接受的变化。这些研究结果总结了 BOP 的多种应用,如紫外线屏蔽或保护层、食品包装,以及用 BOP 取代化肥向植物输送有机物质等。
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