Fatigue Behavior of Medium Entropy Alloys AlCrFe2Ni2 and AlCrFe2Ni2Mo0.1 - A Comparison with Super Duplex Steel 1.4517

Susanne Hemes, Sergej Gein, Niloofar Navaeilavasani, Ulrike Hecht
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Abstract

In the present study the notched fatigue behavior of two multi-phase medium entropy alloys (MEAs) AlCrFe2Ni2 and AlCrFe2Ni2Mo0.1 was characterized by three-point-bending (3-PB), along with a super-duplex steel 1.4517 as a reference material. An analytical approach for characterizing the fatigue notch factor (kf), based on grain size analysis in combination with finite element modelling (FEM) was used, relating the theory of critical distances (TCD) to the grain size of the material. To validate the approach, for the reference steel, the fatigue notch factor was also determined experimentally by comparing the fatigue behavior of notched and smooth specimens, resulting in an experimentally determined fatigue notch factor (kf) ~ 1.07. The numerically and analytically estimated notch effects increase with decreasing average grain size and vary between ~ 1.07 for the coarse-grained reference material – in very good agreement with the experimental results – and ~ 1.35 for the much more fine-grained AlCrFe2Ni2Mo0.1 medium entropy alloy. Note that these values are significantly lower than the stress concentration factor (kt) ~ 1.58, associated with the notch geometry. Fatigue endurance limits were measured at a fatigue stress ratio R ~ 0.1 (unidirectional stress), but were converted to fatigue amplitudes at R = -1 (σa, R-1, fully reversed stress), to be able to make due comparisons with available literature data, by using the elliptical relationship. The resulting fatigue endurance limit amplitudes for specimens surviving at least 2E+06 cycles for a minimum of three tested samples and including notch effects are σa, R-1 ~ 508 MPa for the AlCrFe2Ni2 alloy, σa, R-1 ~ 540 MPa for the AlCrFe2Ni2Mo0.1 alloy modification and σa, R-1 ~ 400 MPa for the reference super-duplex steel, putting the analyzed MEAs into a very competitive position compared to Cobalt containing multi-phase high or medium entropy alloys as well as commercially available steels.
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中熵合金 AlCrFe2Ni2 和 AlCrFe2Ni2Mo0.1 的疲劳行为 - 与超级双相钢 1.4517 的比较
本研究以超级双相钢 1.4517 为参考材料,通过三点弯曲 (3-PB) 分析了两种多相中等熵合金 (MEA) AlCrFe2Ni2 和 AlCrFe2Ni2Mo0.1 的缺口疲劳行为。根据晶粒尺寸分析结合有限元建模(FEM),采用了一种分析方法来表征疲劳缺口系数(kf),将临界距离理论(TCD)与材料的晶粒尺寸联系起来。为验证该方法,还通过比较缺口试样和光滑试样的疲劳行为,实验确定了参考钢材的疲劳缺口系数(kf)~1.07。数值和分析估算的缺口效应随着平均晶粒尺寸的减小而增大,粗晶粒参考材料的缺口效应约为 1.07(与实验结果非常吻合),而更细晶粒的 AlCrFe2Ni2Mo0.1 中熵合金的缺口效应约为 1.35。请注意,这些数值明显低于与缺口几何形状相关的应力集中系数 (kt) ~ 1.58。疲劳耐久极限是在疲劳应力比 R ~ 0.1(单向应力)条件下测量的,但通过椭圆关系将其转换为 R = -1 条件下的疲劳振幅(σa,R-1,完全反向应力),以便与现有文献数据进行适当比较。在至少三个测试样品的至少 2E+06 个循环中,包括缺口效应在内,试样的疲劳耐久极限振幅分别为:AlCrFe2Ni2 合金的 σa, R-1 ~ 508 MPa;AlCrFe2Ni2Mo0.1合金改性的 σa, R-1 ~ 540 MPa;AlCrFe2Ni2Mo0.1合金改性的 σa, R-1 ~ 540 MPa;AlCrFe2Ni2Mo0.1合金改性的 σa, R-1 ~ 540 MPa。与含钴的多相高熵或中熵合金以及市售钢材相比,分析的 MEA 具有很强的竞争力。
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