Corrosion resistance of chromium coating on the inner surface of EP823-Sh steel cladding

Rafael Sh. Isayev, Pavel Dzhumaev, Irina A. Naumenko, Maria V. Leontieva-Smirnova
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Abstract

The processes of corrosion damage of the inner surface of the cladding are determined by corrosive reagents aggressive with respect to the cladding and the type of fuel used. Reactor irradiation of cladding made of EP823-Sh steel with mixed nitride fuel planned for use in the BREST-OD-300 reactor revealed non-uniform corrosion of the inner surface of the cladding. In this paper, the use of the chromium coating is proposed to prevent the corrosion of the inner surface of the steel fuel cladding. The results of corrosion tests of chromium coating applied to the inner surface of cladding made of EP823-Sh steel by electrolytic deposition are presented. Electron-microscopic studies of the chromium coating on EP823-Sh steel showed no significant signs of corrosion damage when tested in the environment of simulant fission products (CsI+Te) and in liquid lead at 650 °C.
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EP823-Sh 钢包层内表面铬涂层的抗腐蚀性能
包层内表面的腐蚀破坏过程是由对包层和所用燃料类型具有侵蚀性的腐蚀试剂决定的。对计划用于 BREST-OD-300 反应堆的 EP823-Sh 钢包层和混合氮化物燃料进行反应堆辐照后发现,包层内表面的腐蚀并不均匀。本文建议使用铬涂层来防止钢制燃料包壳内表面的腐蚀。本文介绍了通过电解沉积法对 EP823-Sh 钢制覆层内表面进行铬涂层腐蚀试验的结果。对 EP823-Sh 钢铬涂层进行的电子显微镜研究表明,在模拟裂变产物(CsI+Te)环境和 650 °C 下的液态铅环境中进行测试时,没有发现明显的腐蚀破坏迹象。
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