Synergistic effect of co-sputtered tungsten-titanium nitride as electrode material for efficient hybrid supercapacitors

Abstract

The dawn of bimetallic transition metal nitrides has attracted considerable interest as battery grade electrode material for potential energy storage applications. In addition, it is essential to investigate binder-free processes to improve the performance of the fabricated electrodes. In this study, binder-free tungsten‑titanium nitrides (W-TiN) are deposited through RF/DC magnetron co-sputtering onto the conducting nickel foam (NF). SEM, EDX and X-ray diffraction are exploited to investigate surface morphology, elemental composition, and structural properties of sputtered materials. The W-TiN electrodes are characterized through electrochemical investigation in half-cell configuration. The tested W-TiN electrode is further utilized with activated carbon (AC) electrode to develop hybrid supercapacitor device W-TiN//AC. The hybrid device revealed a maximum energy density (E_s) of 88.8 Wh/kg and power density (P_s) 1700 W /kg. To further understand the mechanism of hybrid devices, the capacitive and diffusive contributions are computed using linear and quadradic models. This study provides a new direction to integrate co-sputtered binder-free electrode materials and devices for large scale production of advanced hybrid energy storage devices.