{"title":"Performance improvement tactics of sensitized solar cells based on CuInS2 quantum dots prepared by high temperature hot injection","authors":"","doi":"10.1016/j.ssi.2024.116731","DOIUrl":null,"url":null,"abstract":"<div><div>To reveal the ways and causes of conversion efficiency enhancement for quantum dot-sensitized solar cells (QDSSCs), chalcopyrite structure CuInS<sub>2</sub> quantum dots (QDs) was synthesized in oil phase by the high temperature hot injection method. Then, QDs were transferred from oil phase to water phase with 3-mercaptopropionic acid as a ligand exchange reagent and loaded inducer of QDs. 3-mercaptopropionic acid coated QDs in water phase were sensitized on TiO<sub>2</sub> nanocrystalline thin films to fabricate QDSSCs. The sensitization time of QDs and pH value in QDs solution are two important factors to affect the loading amounts of QDs and performance of the final assembled QDSSCs. Long-time sensitization of QDs on the TiO<sub>2</sub> porous thin film will cause QDs to agglomerate and stack on the film. The pH of QDs aqueous solution influences the stable existence in solution of QDs and adsorption on the surface of TiO<sub>2</sub>. By balancing the influence of the above two factors, the optimal sensitization condition of CuInS<sub>2</sub> QDs is adsorption in pH = 11 QDs solution for 2 h. In addition, the interface between QD-sensitized TiO<sub>2</sub> porous thin film and FTO is another factor to affect the photoelectric conversion efficiency of QDSSCs. By adding Zn-doped TiO<sub>2</sub> compact layer with high conductivity and electron mobility on QDSSCs to modify this interface, the photoelectric conversion efficiency of QDSSCs was further increased by 66.4 %.</div></div>","PeriodicalId":431,"journal":{"name":"Solid State Ionics","volume":null,"pages":null},"PeriodicalIF":3.0000,"publicationDate":"2024-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Ionics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167273824002790","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
To reveal the ways and causes of conversion efficiency enhancement for quantum dot-sensitized solar cells (QDSSCs), chalcopyrite structure CuInS2 quantum dots (QDs) was synthesized in oil phase by the high temperature hot injection method. Then, QDs were transferred from oil phase to water phase with 3-mercaptopropionic acid as a ligand exchange reagent and loaded inducer of QDs. 3-mercaptopropionic acid coated QDs in water phase were sensitized on TiO2 nanocrystalline thin films to fabricate QDSSCs. The sensitization time of QDs and pH value in QDs solution are two important factors to affect the loading amounts of QDs and performance of the final assembled QDSSCs. Long-time sensitization of QDs on the TiO2 porous thin film will cause QDs to agglomerate and stack on the film. The pH of QDs aqueous solution influences the stable existence in solution of QDs and adsorption on the surface of TiO2. By balancing the influence of the above two factors, the optimal sensitization condition of CuInS2 QDs is adsorption in pH = 11 QDs solution for 2 h. In addition, the interface between QD-sensitized TiO2 porous thin film and FTO is another factor to affect the photoelectric conversion efficiency of QDSSCs. By adding Zn-doped TiO2 compact layer with high conductivity and electron mobility on QDSSCs to modify this interface, the photoelectric conversion efficiency of QDSSCs was further increased by 66.4 %.
期刊介绍:
This interdisciplinary journal is devoted to the physics, chemistry and materials science of diffusion, mass transport, and reactivity of solids. The major part of each issue is devoted to articles on:
(i) physics and chemistry of defects in solids;
(ii) reactions in and on solids, e.g. intercalation, corrosion, oxidation, sintering;
(iii) ion transport measurements, mechanisms and theory;
(iv) solid state electrochemistry;
(v) ionically-electronically mixed conducting solids.
Related technological applications are also included, provided their characteristics are interpreted in terms of the basic solid state properties.
Review papers and relevant symposium proceedings are welcome.