The Effects of Some Factors on the Electrical Properties of Cu2O/ZnO Double Films Fabricated by Chemical Vapor Deposition Method

Triệu Thị Nguyệt, Do Huy Hoang, Nguyễn Mạnh Hùng, Vu Thi Bich Ngoc, Phạm Anh Sơn
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Abstract

The Cu2O/ZnO double films were fabricated using chemical vapor deposition technique from zinc pivalate and copper(II) acetylacetonate precursors. The crystalline phase composition of the films was examined by powder X-ray diffraction. The membrane surface morphology was studied by scanning electron microscope and atomic force microscope. Film thickness was measured on a surface profilometer. The electrical properties of the fabricated films, such as mobility and carrier concentration, and resistivity are determined by the Hall effect measurement method. The obtained results show that the double film consists of a Cu2O crystal layer with a cubic structure grown on a ZnO crystal layer, with an uneven surface. Cu2O/ZnO double film with Cu2O layer deposited at 240 oC has the best electrical properties. The electrical properties of the double film are better as the Cu2O layer thickness increases: the carrier concentration is highest, and the mobility is lowest when the thickness of Cu2O layer is 474 nm, the resistivity decreases as the Cu2O layer thickness increases.
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一些因素对化学气相沉积法制备的 Cu2O/ZnO 双层薄膜电学特性的影响
利用化学气相沉积技术,以特戊酸锌和乙酰丙酮酸铜(II)为前驱体,制备出了 Cu2O/ZnO 双层薄膜。通过粉末 X 射线衍射检查了薄膜的晶相组成。用扫描电子显微镜和原子力显微镜研究了膜的表面形态。用表面轮廓仪测量了薄膜厚度。利用霍尔效应测量方法测定了所制备薄膜的电学特性,如迁移率、载流子浓度和电阻率。结果表明,双层薄膜由生长在氧化锌晶体层上的立方结构的氧化铜晶体层组成,表面凹凸不平。在 240 oC 下沉积 Cu2O 层的 Cu2O/ZnO 双层薄膜具有最佳的电气性能。双层薄膜的电学特性随着 Cu2O 层厚度的增加而改善:当 Cu2O 层厚度为 474 nm 时,载流子浓度最高,迁移率最低,电阻率随着 Cu2O 层厚度的增加而降低。
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