Assessing the removal efficiency of microplastics: A comparative study using nanosized biochars derived from sustainable sources

Safe ELdeen M.E. Mahmoud , Tarek M. Abdel-Fattah , Mohamed E. Mahmoud , Eva Díaz
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Abstract

The industrial use of plastic materials has led to the production of microplastics, posing significant environmental risks. Microplastic pollution, especially in water systems, has prompted efforts to develop effective removal methods. Therefore, the purpose of this study is devoted to accomplish a novel comparative assessment analysis for the efficacy of two distinct nanosized biochars in removal of polystyrene microplastics (PS-MPs) from aquatic systems by using the batch removal mode. The two selected nanosized biochars, denoted as PAB-NB and AL-NB, were derived from the pyrolysis of pineapple peels and artichoke leaves, respectively. Characterization techniques confirmed the composition and surface properties of the nanobiosorbents. Results showed that both PAB-NB and AL-NB exhibited efficient removal of PS-MPs, with AL-NB demonstrating slightly higher removal capacity. Adsorption processes were found to follow Langmuir monolayer and Freundlich multilayer formations on PAB-NB and AL-NB, respectively. Kinetic studies suggested pseudo1st and pseudo-2nd order models for AL-NB and PAB-NB, respectively. At pH 2.0, both nanobiosorbents showed high removal rates, indicating neutralization of surface charges. These findings suggest that renewable nanobiosorbents derived from biomass wastes, free from metallic contaminants, hold promise for effective removal of polystyrene pollutants, offering a sustainable solution to prevent microplastic pollution in water systems.

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评估微塑料的去除效率:使用可持续来源的纳米生物炭进行比较研究
塑料材料的工业化使用导致了微塑料的产生,对环境造成了重大风险。微塑料污染,尤其是水系统中的微塑料污染,促使人们努力开发有效的去除方法。因此,本研究的目的是采用批量去除模式,对两种不同的纳米生物炭去除水生系统中的聚苯乙烯微塑料(PS-MPs)的功效进行新颖的比较评估分析。所选的两种纳米生物炭(分别称为 PAB-NB 和 AL-NB)来自菠萝皮和朝鲜蓟叶的热解。表征技术证实了纳米生物吸附剂的组成和表面特性。结果表明,PAB-NB 和 AL-NB 都能有效地去除 PS-MPs,其中 AL-NB 的去除能力略高。研究发现,PAB-NB 和 AL-NB 上的吸附过程分别遵循 Langmuir 单层和 Freundlich 多层吸附形式。动力学研究表明,AL-NB 和 PAB-NB 分别具有假 1 阶和假 2 阶模型。在 pH 值为 2.0 时,两种纳米生物吸附剂都显示出较高的去除率,这表明表面电荷得到了中和。这些研究结果表明,从生物质废物中提取的可再生纳米生物吸附剂不含金属污染物,有望有效去除聚苯乙烯污染物,为防止水系统中的微塑料污染提供了一种可持续的解决方案。
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来源期刊
Environmental Nanotechnology, Monitoring and Management
Environmental Nanotechnology, Monitoring and Management Environmental Science-Water Science and Technology
CiteScore
13.00
自引率
0.00%
发文量
132
审稿时长
48 days
期刊介绍: Environmental Nanotechnology, Monitoring and Management is a journal devoted to the publication of peer reviewed original research on environmental nanotechnologies, monitoring studies and management for water, soil , waste and human health samples. Critical review articles, short communications and scientific policy briefs are also welcome. The journal will include all environmental matrices except air. Nanomaterials were suggested as efficient cost-effective and environmental friendly alternative to existing treatment materials, from the standpoints of both resource conservation and environmental remediation. The journal aims to receive papers in the field of nanotechnology covering; Developments of new nanosorbents for: •Groundwater, drinking water and wastewater treatment •Remediation of contaminated sites •Assessment of novel nanotechnologies including sustainability and life cycle implications Monitoring and Management papers should cover the fields of: •Novel analytical methods applied to environmental and health samples •Fate and transport of pollutants in the environment •Case studies covering environmental monitoring and public health •Water and soil prevention and legislation •Industrial and hazardous waste- legislation, characterisation, management practices, minimization, treatment and disposal •Environmental management and remediation
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