{"title":"Laser-zoned treatment of magnesium surfaces with predictable degradation applications","authors":"","doi":"10.1016/j.surfcoat.2024.131300","DOIUrl":null,"url":null,"abstract":"<div><div>Magnesium metal is a promising material for medical applications due to its biocompatibility and similar modulus of elasticity to human bone. However, its complex corrosion process must be addressed before it can be used clinically to match post-implantation tissue repair. This study aims to regulate material degradation by utilizing laser surface treatment. The surface of pure magnesium was modified using nanosecond and femtosecond laser methods to create various micro-nanostructures, such as chain, streak, column, and groove structures. Surface roughness and wettability tests revealed that the groove structures had higher roughness values. All structures exhibited hydrophilicity, but the femtosecond laser-generated structures were more hydrophilic. Electrochemical tests and immersion experiments demonstrated that femtosecond laser modification significantly improved the corrosion resistance of magnesium metal compared to polished samples. Cytotoxicity experiments showed that the laser-treated magnesium was not cytotoxic. Based on the results, we constructed various structures on the magnesium rods in different regions. As a result, the rods exhibited multi-stage biodegradation behavior in simulated body fluids (SBF). This study presents a novel approach to controlling the degradation sequence of medical metals.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":null,"pages":null},"PeriodicalIF":5.3000,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface & Coatings Technology","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0257897224009319","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
引用次数: 0
Abstract
Magnesium metal is a promising material for medical applications due to its biocompatibility and similar modulus of elasticity to human bone. However, its complex corrosion process must be addressed before it can be used clinically to match post-implantation tissue repair. This study aims to regulate material degradation by utilizing laser surface treatment. The surface of pure magnesium was modified using nanosecond and femtosecond laser methods to create various micro-nanostructures, such as chain, streak, column, and groove structures. Surface roughness and wettability tests revealed that the groove structures had higher roughness values. All structures exhibited hydrophilicity, but the femtosecond laser-generated structures were more hydrophilic. Electrochemical tests and immersion experiments demonstrated that femtosecond laser modification significantly improved the corrosion resistance of magnesium metal compared to polished samples. Cytotoxicity experiments showed that the laser-treated magnesium was not cytotoxic. Based on the results, we constructed various structures on the magnesium rods in different regions. As a result, the rods exhibited multi-stage biodegradation behavior in simulated body fluids (SBF). This study presents a novel approach to controlling the degradation sequence of medical metals.
期刊介绍:
Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance:
A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting.
B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.