Numerical study of a bamboo-like micro-tubular solid oxide fuel cell

IF 8.1 2区 工程技术 Q1 CHEMISTRY, PHYSICAL International Journal of Hydrogen Energy Pub Date : 2024-09-14 DOI:10.1016/j.ijhydene.2024.09.037
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Abstract

An innovative structure of segmented-in-series tubular solid oxide fuel cell, the bamboo-like optimized the current collection and achieve higher power density compared with that of the cell with the same axial length. In this study, a comprehensive three-dimensional (3D) numerical model of a bamboo-like micro-tubular solid oxide fuel cell (uT-SOFC) coupling the electrochemical reactions and mass, momentum, heat transfer processes and thermal stress, is developed by using the finite element method for the first time. Investigating the internal conditions under steady-state conditions to understand mass transfer, heat transfer processes, and mechanical states of the bamboo-like uT-SOFCs. The steam flow exhibits limited diffusion in the region of the anode at the internal end of the interconnector, creating a concentration gradient of H2O that adversely affects the cell performance. The maximum mole fraction of H2O in this region of two-cells and three-cells in series is increased by 185 % and 112 % respectively compared to the overall average of the cells. The interconnector shortens the current transmission path of the cells, and exhibits high current collection efficiency. This structure achieves a lower temperature while attaining higher power density compared to the same axial length cell at 973 K. The temperature of three-cells in series decreased by 3 K–5 K compared with two-cells in series. The thermal stress induced by the interconnector on the cells is minor, and the thermal expansion displacement caused by the interconnector is only approximately 7 μm–8 μm. This study revealed its internal conditions, and provides an insight into the bamboo-like structure.

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竹状微管固体氧化物燃料电池的数值研究
作为一种分段串联管状固体氧化物燃料电池的创新结构,与具有相同轴向长度的电池相比,类竹节优化了电流收集并实现了更高的功率密度。本研究首次采用有限元法建立了竹节状微管固体氧化物燃料电池(uT-SOFC)的综合三维(3D)数值模型,将电化学反应与质量、动量、传热过程和热应力耦合在一起。研究稳态条件下的内部条件,以了解竹节状 uT-SOFC 的传质、传热过程和机械状态。蒸汽流在互联器内端阳极区域的扩散受到限制,形成了对电池性能产生不利影响的 H2O 浓度梯度。与电池的整体平均值相比,串联的两个电池和三个电池在该区域的 H2O 最大摩尔分数分别增加了 185% 和 112%。互联器缩短了电池的电流传输路径,并表现出很高的电流收集效率。在 973 K 温度条件下,与相同轴向长度的电池相比,这种结构的温度更低,同时功率密度更高。互联器对电池产生的热应力很小,互联器引起的热膨胀位移仅约为 7 μm-8 μm。这项研究揭示了其内部条件,并提供了对竹状结构的深入了解。
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来源期刊
International Journal of Hydrogen Energy
International Journal of Hydrogen Energy 工程技术-环境科学
CiteScore
13.50
自引率
25.00%
发文量
3502
审稿时长
60 days
期刊介绍: The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc. The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.
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