Sustainable Hydrogen Production with Synergistic Electron Transfer Enhancement in Nickel-Based Alkaline HER Electrocatalyst Empowered by Graphene Oxide

Abstract

The hydrogen evolution reaction (HER) plays a crucial role in driving forward the transition to a hydrogen-based economy by providing a means to generate pure hydrogen. However, the efficient and cost-effective production of hydrogen via HER faces significant challenges, particularly at the cathode. To address these challenges, we produced a hybrid material – 2D graphene oxide (GO) sheets coated onto nickel sulfide (NiS) microspheres anchored on Ni Foam (GO@NiS/Ni Foam) using a straightforward synthesis technique. Our research highlights the significant influence of the interaction between GO and NiS on the performance of HER, attributed to the enhancement of electron transport at the interface. Furthermore, the GO@NiS/Ni Foam composite exhibits remarkable durability over extended periods, maintaining its superior functionality for up to 40 hours of continuous operation. This underscores its potential for practical implementation in efficient water-splitting processes, offering a promising solution to the challenges hindering widespread adoption of hydrogen technology.