Machine Learning-Based Prediction of the Adsorption Characteristics of Biochar from Waste Wood by Chemical Activation.

Abstract

This study employs machine learning models to predict the adsorption characteristics of biochar-activated carbon derived from waste wood. Activated carbon is a high-performance adsorbent utilized in various fields such as air purification, water treatment, energy production, and storage. However, its characteristics vary depending on the activation conditions or raw materials, making explaining or predicting them challenging using physicochemical or mathematical methods. Therefore, using machine learning techniques to determine the adsorption characteristics of activated carbon in advance will provide economic and time benefits for activated carbon production. Datasets, consisting of 108 points, were used to predict the adsorption characteristics of biochar-activated carbon derived from waste wood. The input variables were the activation conditions, and the iodine number of activated carbon was used as the output variable. The datasets were randomly split into 75% for training and 25% for model validation and normalized by the min-max function. Four models, including artificial neural networks, random forests, extreme gradient boosting, and support vector machines, were used to predict the adsorption properties of biochar-activated carbon. After optimization, the artificial neural network model was identified as the best model, with the highest coefficient determination (0.96) and the lowest mean squared error (0.004017). As a result of the SHAP analysis, activation time was the most crucial variable influencing the adsorption properties. The machine learning model precisely predicts the adsorption characteristics of biochar-activated carbon and can optimize the activated carbon production process.