Influence of Grinding Aids on the Grinding Performance and Rheological Properties of Cementitious Systems.

IF 3.1 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Materials Pub Date : 2024-10-31 DOI:10.3390/ma17215328
Yahya Kaya, Hatice Gizem Şahin, Naz Mardani, Ali Mardani
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Abstract

The cement industry is of great importance in terms of raw materials consumed, energy consumed, and greenhouse gases emitted. Grinding aids (GA) are used to reduce energy consumption and costs, as well as to reduce the amount of CO2 released into the environment. In this study, the effect of GA-polycarboxylate ether-based water-reducing admixture (PCE) compatibility on some fresh, rheological and hardened state properties of cementitious systems was investigated. In order to investigate the rheological properties and thixotropic behavior of the mixtures, a total of 51 cement paste mixtures were prepared, containing 4 different types (molasses, MEG, DEA and ethanol) and ratios (0.025, 0.05, 0.75 and 0.1) of GAs and 2 different ratios (0.08% and 0.16%) of PCE in addition to the control mixture. In addition, the effect of the used GAs on the grinding efficiency and compressive strength value was investigated. Additionally, the predictability of the type of GA, dosage and cure time using the Taguchi method was investigated. It was determined that the highest grinding performance was obtained in mixtures containing MEG. It was determined that in cement paste mixtures containing GAs, the dynamic yield stress and viscosity values generally decrease with the increase in PCE usage rate up to a certain value, and these values may increase if the PCE usage increases further. It was determined that such behavior is not present in cement paste mixtures containing GAs and that the structural build-up value of the mixtures generally increases with the increase in the PCE admixture usage rate. It was determined that the use of GAs had a positive effect on 28-day compressive strength.

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研磨助剂对水泥基体系研磨性能和流变特性的影响。
水泥工业在原材料消耗、能源消耗和温室气体排放方面具有重要意义。使用助磨剂(GA)不仅可以降低能耗和成本,还能减少排放到环境中的二氧化碳量。本研究调查了 GA-聚羧酸醚基减水剂(PCE)相容性对水泥基体系的一些新鲜、流变和硬化状态性能的影响。为了研究混合物的流变特性和触变性能,共制备了 51 种水泥浆混合物,其中除对照混合物外,还含有 4 种不同类型(糖蜜、MEG、DEA 和乙醇)和比率(0.025、0.05、0.75 和 0.1)的 GA 和 2 种不同比率(0.08% 和 0.16%)的 PCE。此外,还研究了所使用的 GAs 对研磨效率和抗压强度值的影响。此外,还采用田口方法研究了 GA 类型、用量和固化时间的可预测性。结果表明,含有 MEG 的混合物具有最高的碾磨性能。研究还确定,在含有 GA 的水泥浆混合物中,动态屈服应力和粘度值通常会随着 PCE 用量的增加而降低,直至达到一定值;如果 PCE 用量进一步增加,这些值可能会升高。经测定,含有 GAs 的水泥浆混合物不存在这种行为,而且混合物的结构堆积值通常会随着 PCE 掺合料用量的增加而增加。研究还确定,使用 GAs 对 28 天抗压强度有积极影响。
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来源期刊
Materials
Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
5.80
自引率
14.70%
发文量
7753
审稿时长
1.2 months
期刊介绍: Materials (ISSN 1996-1944) is an open access journal of related scientific research and technology development. It publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Materials provides a forum for publishing papers which advance the in-depth understanding of the relationship between the structure, the properties or the functions of all kinds of materials. Chemical syntheses, chemical structures and mechanical, chemical, electronic, magnetic and optical properties and various applications will be considered.
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