Zhi-Yuan Wei , Yao Cai , Feng-Guang Li , Hai-Ming Huang , Min Wang
{"title":"Heterogeneous multilayered delamination of thermally grown oxide accelerating spallation of thermal barrier coatings","authors":"Zhi-Yuan Wei , Yao Cai , Feng-Guang Li , Hai-Ming Huang , Min Wang","doi":"10.1016/j.ceramint.2024.09.275","DOIUrl":null,"url":null,"abstract":"<div><div>Long lifetime of thermal barrier coatings (TBCs) is limited by the localized thermally grown oxide (TGO) accumulation. Herein, the heterogeneous multilayered delamination mechanism of TGO is revealed. TGO cracking preferentially occurs at the peak of bond coat due to mismatch and extends toward the flank region under TGO growth. The thinner sublayer after first delamination is mainly attributed to loss of ceramic constraint. The delamination accumulation increases the YSZ crack driving force and provides a fast propagation channel for YSZ crack to pass through TGO. These results provide a guidance for the development of advanced TBC with higher oxidation resistance.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"50 23","pages":"Pages 49300-49310"},"PeriodicalIF":5.1000,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884224042937","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
Long lifetime of thermal barrier coatings (TBCs) is limited by the localized thermally grown oxide (TGO) accumulation. Herein, the heterogeneous multilayered delamination mechanism of TGO is revealed. TGO cracking preferentially occurs at the peak of bond coat due to mismatch and extends toward the flank region under TGO growth. The thinner sublayer after first delamination is mainly attributed to loss of ceramic constraint. The delamination accumulation increases the YSZ crack driving force and provides a fast propagation channel for YSZ crack to pass through TGO. These results provide a guidance for the development of advanced TBC with higher oxidation resistance.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.