Regulation of receptor function in NiCo2O4-SnO2 heterojunction for H2S detection at room temperature

Abstract

In recent years, the World Health Organization has increasingly emphasized air quality in production environments, leading to heightened societal demands for monitoring of pollutant gases at room temperature. Traditional semiconductor gas-sensitive materials, such as tin oxide (SnO₂), have their gas-sensing performance largely limited by their receptor functions, resulting in common issues like low response and poor recovery at room temperature. Spinel-type bimetallic oxides, such as nickel cobaltate (NiCo₂O₄), offer a unique solution due to their rich adsorption sites on the surface, which provide distinctive receptor functions for detecting toxic gases at room temperature. Herein, NiCo₂O₄ is synthesized via a one-step hydrothermal method, with a porous spherical cluster structure, and combined with SnO₂ to form a heterojunction. The NiCo₂O₄-SnO₂ heterojunction film gas sensor exhibits excellent gas-sensing performance for H₂S at room temperature, including high response, short response time, good repeatability, and selectivity. Additionally, the unique receptor functions of the NiCo₂O₄ were analyzed through first-principles calculations, revealing a semiconductor p-n conversion phenomenon in the presence of H₂S gas. The composite also demonstrates a conversion from p-n heterojunction to n-n homojunction during the sensing process, enhancing its gas-sensing performance. This work not only addresses the receptor function limitations of traditional gas-sensitive semiconductor but also provides a feasible approach for controlling carrier types in semiconductors.