{"title":"Current density and thickness dependent anisotropic thermal conductivity of electroplated copper thin films","authors":"Hongbang Zhang , Song Hu , Miao Tian , Xiaokun Gu","doi":"10.1016/j.mssp.2024.109152","DOIUrl":null,"url":null,"abstract":"<div><div>Electroplated copper thin films are essential in microelectronics, widely used for back-end interconnects, through-silicon vias, and redistribution layers. Currently, their thermal conductivity is frequently estimated indirectly using the four-point probe method and the Wiedemann-Franz law, with limited research on their anisotropy and influencing factors. In this paper, we report the measurements on the electrical and thermal properties of electroplated copper thin films under different current densities during plating and thicknesses using the four-point probe method and frequency-domain thermoreflectance. The results indicate that current density and film thickness significantly influence the microstructure of the copper thin films, resulting in pronounced anisotropy in thermal conductivity. Scanning electron microscopy and electron backscatter diffraction analyses further reveal the microstructural features responsible for this anisotropy and explain how current density affects the internal structure of electroplated copper films, impacting their thermal conductivity. These insights provide valuable theoretical guidance for designing and optimizing electroplated copper films in electronic applications.</div></div>","PeriodicalId":18240,"journal":{"name":"Materials Science in Semiconductor Processing","volume":"187 ","pages":"Article 109152"},"PeriodicalIF":4.2000,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science in Semiconductor Processing","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1369800124010485","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
Electroplated copper thin films are essential in microelectronics, widely used for back-end interconnects, through-silicon vias, and redistribution layers. Currently, their thermal conductivity is frequently estimated indirectly using the four-point probe method and the Wiedemann-Franz law, with limited research on their anisotropy and influencing factors. In this paper, we report the measurements on the electrical and thermal properties of electroplated copper thin films under different current densities during plating and thicknesses using the four-point probe method and frequency-domain thermoreflectance. The results indicate that current density and film thickness significantly influence the microstructure of the copper thin films, resulting in pronounced anisotropy in thermal conductivity. Scanning electron microscopy and electron backscatter diffraction analyses further reveal the microstructural features responsible for this anisotropy and explain how current density affects the internal structure of electroplated copper films, impacting their thermal conductivity. These insights provide valuable theoretical guidance for designing and optimizing electroplated copper films in electronic applications.
期刊介绍:
Materials Science in Semiconductor Processing provides a unique forum for the discussion of novel processing, applications and theoretical studies of functional materials and devices for (opto)electronics, sensors, detectors, biotechnology and green energy.
Each issue will aim to provide a snapshot of current insights, new achievements, breakthroughs and future trends in such diverse fields as microelectronics, energy conversion and storage, communications, biotechnology, (photo)catalysis, nano- and thin-film technology, hybrid and composite materials, chemical processing, vapor-phase deposition, device fabrication, and modelling, which are the backbone of advanced semiconductor processing and applications.
Coverage will include: advanced lithography for submicron devices; etching and related topics; ion implantation; damage evolution and related issues; plasma and thermal CVD; rapid thermal processing; advanced metallization and interconnect schemes; thin dielectric layers, oxidation; sol-gel processing; chemical bath and (electro)chemical deposition; compound semiconductor processing; new non-oxide materials and their applications; (macro)molecular and hybrid materials; molecular dynamics, ab-initio methods, Monte Carlo, etc.; new materials and processes for discrete and integrated circuits; magnetic materials and spintronics; heterostructures and quantum devices; engineering of the electrical and optical properties of semiconductors; crystal growth mechanisms; reliability, defect density, intrinsic impurities and defects.